cis-diethyl 2-hydroxy-2-(2-decenyl)propane-1,3-dioate | 90046-87-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: cis-diethyl 2-hydroxy-2-(2-decenyl)propane-1,3-dioate
• CAS: 90046-87-0
• 化学式: C₁₇H₃₀O₅
• 分子量: 314.422
• InChiKey: LIPLHKSJZDPTOC-SEYXRHQNSA-N

物化性质

• 沸点：
  384.7±37.0 °C(Predicted)
• 密度：
  1.023±0.06 g/cm3(Predicted)

反应信息

• 作为产物：
  描述：

  正癸烯 、 酮基丙二酸二乙酯 反应 5.0h， 生成 cis-diethyl 2-hydroxy-2-(2-decenyl)propane-1,3-dioate 、 trans-diethyl 2-hydroxy-2-(2-decenyl)propane-1,3-dioate
  参考文献：
  名称：

  Specific activation by microwaves: myth or reality?

  摘要：

  Ene reactions involving carbonyl enophiles have been carried out under microwave irradiation at controlled temperature and atmospheric pressure. The reactions of diethyl mesoxalate with 1-decene and beta-pinene and the cyclization of (+)-citronellal under homogeneous (neat liquid) or heterogeneous (clay catalyst) conditions have been studied. In each case the dependence of reaction yield on time and the stereoisomer ratios of the products are unaffected by the heating mode.

  DOI：

  10.1021/jo00052a022

文献信息

• Garrigues, Bernard; Laurent, Regis; Laporte, Christian, Liebigs Annalen, 1996, # 5, p. 743 - 744
  作者：Garrigues, Bernard、Laurent, Regis、Laporte, Christian、Laporterie, Andre、Dubac, Jacques

  DOI：——

  日期：——