| 301153-68-4

• CAS: 301153-68-4
• 化学式: C₂₇H₂₆N₂O₄P₂Pd
• 分子量: 610.882
• InChiKey: LWAOJHGLFVMKOM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  silver(I) nitrite 、 bis(acetonitrile)palladium(II) dichloride 、 1,2-双(二苯基膦)乙烷 以 乙腈 为溶剂， 生成 、
  参考文献：
  名称：

  Preparation and solution behavior of diphosphinepalladium nitrite complexes

  摘要：

  Diphosphinepalladium nitrite complexes of the type [Pd(NO2)(2)L-2] (L-2 = dppm, dppe, dppp) have been prepared by treatment of [PdCl2(CH3CN)(2)] with silver nitrite, followed by addition of the appropriate diphosphine. The nitrite complexes are fluxional in solution at 298 K, but on cooling to 220 K signals due to three species could be detected. These have been assigned to the N-bonded, the O-bonded, and the mixed coordination compounds. Treatment of [PdCl2(dppe)] with two equivalents of TlPF6, followed by addition of (NaNO2)-N-15, produced [Pd((NO2)-N-15)(2)(dppe)], whose P-31 NMR spectrum allowed identification of the three isomers. The analogous platinum complex [Pt(NO2)(2)(dppe)] exists as a single isomer, which is static at 298 K, and a (NO2)-N-15-labeling experiment indicated that it contains N-bonded nitrite ligands. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00407-1