(4'-Propyl-bicyclohexyl-4-yl)-acetyl chloride | 96143-30-5

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 酰卤
• 英文名称: (4'-Propyl-bicyclohexyl-4-yl)-acetyl chloride
• CAS: 96143-30-5
• 化学式: C₁₇H₂₉ClO
• 分子量: 284.87
• InChiKey: WIIDKYDLGQDXQI-BIAGXBKMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.55
• 重原子数：
  19.0
• 可旋转键数：
  5.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  17.07
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  乙基溴化镁 、 (4'-Propyl-bicyclohexyl-4-yl)-acetyl chloride 在 iron(III)-acetylacetonate 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 1.0h， 生成 1-(4'-Propyl-bicyclohexyl-4-yl)-butan-2-one
  参考文献：
  名称：

  Synthesis and Some Physical Properties of Bicyclohexanes Having Fluoro Substituted Alkyl Moiety

  摘要：

  The influence of introducing fluorine atoms into alkyl chains of dialkylbicyclohexanes on their physical properties has been investigated. Wide mesophase ranges of the bicyclohexanes were induced by the fluorine atoms. Their viscosity changed depending on the position of fluorine atoms on the alkyl chains and some of the fluorinated bicyclohexanes showed low viscosity. Also dielectric anisotropy and birefringence increased by introducing fluorine atoms. By using the fluorinated compounds mixtures for TFT and STN applications having attractive properties; a wide mesophase range, lower viscosity and higher specific resistivity could be obtained.

  DOI：

  10.1080/10587259508038701
• 作为产物：
  描述：

  (4'-Propyl-bicyclohexyl-4-yl)-acetic acid 在 氯化亚砜 作用下， 反应 3.0h， 生成 (4'-Propyl-bicyclohexyl-4-yl)-acetyl chloride
  参考文献：
  名称：

  Synthesis and Some Physical Properties of Bicyclohexanes Having Fluoro Substituted Alkyl Moiety

  摘要：

  The influence of introducing fluorine atoms into alkyl chains of dialkylbicyclohexanes on their physical properties has been investigated. Wide mesophase ranges of the bicyclohexanes were induced by the fluorine atoms. Their viscosity changed depending on the position of fluorine atoms on the alkyl chains and some of the fluorinated bicyclohexanes showed low viscosity. Also dielectric anisotropy and birefringence increased by introducing fluorine atoms. By using the fluorinated compounds mixtures for TFT and STN applications having attractive properties; a wide mesophase range, lower viscosity and higher specific resistivity could be obtained.

  DOI：

  10.1080/10587259508038701

文献信息

• Heterocyclic derivatives
  申请人：MERCK PATENT GmbH

  公开号：EP0519370B1

  公开（公告）日：1997-11-05
• Cyclohexane derivative and liquid crystal composition containing same
  申请人：Chisso Corporation

  公开号：EP0205998B1

  公开（公告）日：1990-02-28
• Cyclohexane derivatives
  申请人：Chisso Corporation

  公开号：EP0316715B1

  公开（公告）日：1992-06-03
• US4797228A
  申请人：——

  公开号：US4797228A

  公开（公告）日：1989-01-10
• US4853152A
  申请人：——

  公开号：US4853152A

  公开（公告）日：1989-08-01