2,2,4,4,6,6-hexzakis-(2'-azido-1'-ethoxy)-cyclotriphosphazatriene | 1430224-19-3

• 分子结构分类: 有机化合物 - 有机卤素化合物
• 英文名称: 2,2,4,4,6,6-hexzakis-(2'-azido-1'-ethoxy)-cyclotriphosphazatriene
• 英文别名: 2,2,4,4,6,6-Hexakis(2-azidoethoxy)-1,3,5-triaza-2lambda5,4lambda5,6lambda5-triphosphacyclohexa-1,3,5-triene；2,2,4,4,6,6-hexakis(2-azidoethoxy)-1,3,5-triaza-2λ5,4λ5,6λ5-triphosphacyclohexa-1,3,5-triene
• CAS: 1430224-19-3
• 化学式: C₁₂H₂₄N₂₁O₆P₃
• 分子量: 651.381
• InChiKey: OESLLMRSSGLKNU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  42
• 可旋转键数：
  24
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  179
• 氢给体数：
  0
• 氢受体数：
  21

反应信息

• 作为反应物：
  描述：

  2,2,4,4,6,6-hexzakis-(2'-azido-1'-ethoxy)-cyclotriphosphazatriene 、 C₂₅H₂₇NO 在 五甲基二乙烯三胺 、 copper(I) bromide 作用下， 以 二氯甲烷 为溶剂， 反应 48.0h， 以61.13%的产率得到C₁₆₂H₁₈₆N₂₇O₁₂P₃
  参考文献：
  名称：

  Syntheses, characterizations, thermal and photophysical properties of cyclophosphazenes containing adamantane units

  摘要：

  In this study, phenoxy-adamantane substituted cyclophosphazene compounds (5-8) were synthesized in three steps. Firstly; adamantane derivatives (1 and 2) containing alkyne groups were prepared. Secondly; 2,2,4,4,6,6-hexzakis-(2'-azido-1'-ethoxy)-cyclotriphosphazatriene (3) and 2,2,4,4,6,6,8,8-octakis-(2'-azido-1'-ethoxy)-cyclotetraphosphazatetraene (4) were synthesized from the nucleophilic substitutions of 2-azido-1-ethanol with trimer (N3P3Cl6) and tetramer (N4P4Cl8) in THF respectively. Thirdly; cyclophosphazenes containing adamantane units (5-8) were obtained by the Cu(I) catalyzed click reactions of cyclophosphazenes (3 and 4) with compounds 1 and 2. The structural investigations of newly synthesized compounds 1-8 were evaluated by elemental analysis and FT-IR (ATR), mass spectrometry, H-1, C-13, H-1-C-13 HSQC (for 6) and P-31 NMR (for 3-8) spectroscopies. Compound 1-8 were also reported for the first time. The thermal and photophysical properties of 5-8 were investigated. (C) 2013 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.01.028
• 作为产物：
  描述：

  2-叠氮基乙醇 在 六氯环三磷腈 、 sodium hydride 作用下， 以 四氢呋喃 、 mineral oil 为溶剂， 生成 2,2,4,4,6,6-hexzakis-(2'-azido-1'-ethoxy)-cyclotriphosphazatriene
  参考文献：
  名称：

  基于环三磷腈核的六-BODIPY联苯并三唑作为对Fe离子的高度选择性和灵敏的荧光传感器。

  摘要：

  设计并合成了一种新型的基于三唑基团连接的六硼联吡啶并亚甲基环三磷腈平台（HBTC）的荧光化学传感器。通过紫外可见和荧光光谱研究了其对金属离子的传感行为。在HBTC的四氢呋喃溶液中添加Fe2 +离子会产生可见的颜色变化，并显着淬灭荧光发射，而其他测试的19种金属离子则不会引起颜色或光谱变化。据发现，该化合物对Fe2 +具有高选择性和敏感性，并且检测限较低（2.03μM），据我们所知，它比先前研究的Fe2 +化学传感器优越。图形概要 。

  DOI：

  10.1007/s10895-016-1797-0

文献信息

• Silicon-based energy storage devices with phosphazene containing electrolyte additives
  申请人：ENEVATE CORPORATION

  公开号：US11522223B2

  公开（公告）日：2022-12-06

  Electrolytes and electrolyte additives for energy storage devices comprising phosphazene based compounds are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte comprising at least two electrolyte co-solvents, wherein at least one electrolyte co-solvent comprises a phosphazene based compound.

  本发明公开了用于储能装置的电解质和电解质添加剂，其中包含磷苯基化合物。该储能装置包括第一电极和第二电极，其中第一电极和第二电极中的至少一个是硅基电极；第一电极和第二电极之间的隔板；电解液，包括至少两种电解液助溶剂，其中至少一种电解液助溶剂包括磷苯基化合物。
• SILICON-BASED ENERGY STORAGE DEVICES WITH PHOSPHAZENE CONTAINING ELECTROLYTE ADDITIVES
  申请人：ENEVATE CORPORATION

  公开号：US20200136185A1

  公开（公告）日：2020-04-30

  Electrolytes and electrolyte additives for energy storage devices comprising phosphazene based compounds are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte comprising at least two electrolyte co-solvents, wherein at least one electrolyte co-solvent comprises a phosphazene based compound.