(5Z,10Z,14Z,19Z)-5-(4-Hexadecyloxy-phenyl)-10,15,20-tri-p-tolyl-porphyrin | 139377-78-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: (5Z,10Z,14Z,19Z)-5-(4-Hexadecyloxy-phenyl)-10,15,20-tri-p-tolyl-porphyrin
• CAS: 139377-78-9
• 化学式: C₆₃H₆₈N₄O
• 分子量: 897.259
• InChiKey: UWPNRFUMIZFYII-SWPMMZLJSA-N

反应信息

• 作为产物：
  描述：

  溴代十六烷 、 5-(4-hydroxyphenyl)-10,15,20-tri(p-tolyl)porphyrin 在 氢氧化钾 作用下， 以 四氢呋喃 为溶剂， 生成 (5Z,10Z,14Z,19Z)-5-(4-Hexadecyloxy-phenyl)-10,15,20-tri-p-tolyl-porphyrin
  参考文献：
  名称：

  Light-induced electron transfer of porphyrin triad for photoelectric conversion

  摘要：

  Two new triad model compounds of porphyrin-viologen-carbazole (1a and 1b) with different chain length were synthesized to mimic photosynthesis. The absorption and fluorescence spectra in solution, in micelle solution as well as in binary solvent, were investigated; especially, the effects of aggregation on the photophysical properties were investigated. A mechanism including photoinduced electron transfer and two-step charge separation was suggested. These triad compounds were easily formed LB films. Rather high photodriven voltages and currents were obtained with only one monolayer of LB film on the surface of SnO2 conductive glass.

  DOI：

  10.1021/j100186a020