acetylacetonato(22,23,72,73,122,123,172,173-octakis(pyridin-2-yl)tetrapyrazino[b,g,l,q]-5,10,15,20-tetraazaporphyrinato)erbium(III) | 1127415-23-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: acetylacetonato(22,23,72,73,122,123,172,173-octakis(pyridin-2-yl)tetrapyrazino[b,g,l,q]-5,10,15,20-tetraazaporphyrinato)erbium(III)
• CAS: 1127415-23-9
• 化学式: C₅H₇O₂*C₆₄H₃₂N₂₄*Er
• 分子量: 1403.49
• InChiKey: STTLRUKFQHFKGJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.15
• 重原子数：
  96.0
• 可旋转键数：
  10.0
• 环数：
  17.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  345.92
• 氢给体数：
  0.0
• 氢受体数：
  24.0

反应信息

• 作为产物：
  描述：

  tris(acetylacetonate)erbium(III) 、 2,3-dicyano-5,6-di(2-pyridyl)pyrazine 在 sodium methylate 、 尿素 作用下， 以 苯甲腈 为溶剂， 以28%的产率得到acetylacetonato(22,23,72,73,122,123,172,173-octakis(pyridin-2-yl)tetrapyrazino[b,g,l,q]-5,10,15,20-tetraazaporphyrinato)erbium(III)
  参考文献：
  名称：

  Synthesis and properties of lanthanide complexes with tetrapyrazinoporphyrazine and its substituted derivatives

  摘要：

  Reactions of dicyanopyrazine and its tert-butyl-, diphenyl-, and dipyridyl-substituted derivatives with erbium, thulium, ytterbium, and lutetium chlorides, acetates, and acetylacetonates gave the corresponding tetrapyrazinoporphyrazine metal complexes which were characterized by elemental analyses, and IR, H-1 NMR, and electronic absorption spectra. The stability of the complexes to thermooxidative decomposition in air was also studied.

  DOI：

  10.1134/s1070363207110175