Cu(II) 5,10,15,20-tetra[3-(3-phenoxy)-propoxy]phenyl porphyrin | 1235344-49-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: Cu(II) 5,10,15,20-tetra[3-(3-phenoxy)-propoxy]phenyl porphyrin
• CAS: 1235344-49-6
• 化学式: C₈₀H₆₈CuN₄O₈
• 分子量: 1276.99
• InChiKey: RVQVUBFGZNSGTJ-LPVWYINYSA-N

反应信息

• 作为产物：
  描述：

  5,10,15,20-tetra[3-(3-phenoxy)-propoxy]phenyl porphyrin 在 copper dichloride 作用下， 以 乙醇 、 氯仿 为溶剂， 反应 24.0h， 以95%的产率得到Cu(II) 5,10,15,20-tetra[3-(3-phenoxy)-propoxy]phenyl porphyrin
  参考文献：
  名称：

  The photocatalytic activity of novel, substituted porphyrin/TiO2-based composites

  摘要：

  Four novel porphyrins, 5-[3-(3-phenoxy)-propoxy]phenyl porphyrin, 5,15-di-[3-(3-phenoxy)-propoxy] phenyl porphyrin, 5,10,15-tri-[3-(3-phenoxy)-propoxy]phenyl porphyrin, 5,10,15,20-tetra-[3-(3-phenoxy)- propoxy]phenyl porphyrin, and their corresponding Cu(II) porphyrins, were synthesized and characterized spectroscopically. The photodegradation of 4-nitrophenol in aq. suspension was used to determine the photocatalytic activity of polycrystalline TiO2 samples which had been impregnated with the Cu(II) porphyrins, as sensitizers. The photocatalytic activity of the composite depends mainly on the amount of sensitizer on the TiO2 surface rather than the nature of the substituted porphyrins. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2009.08.001