| 243866-66-2

• CAS: 243866-66-2
• 化学式: C₁₇H₂₇FeO₃Si₂*Na
• 分子量: 414.407
• InChiKey: UPGIELHWXWQGJM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  sodium hydroxide 、 sodium hydride 、 triscarbonyl-(η⁴-3,4-bis(4-methoxyphenyl)-2,5-diphenylcyclopenta-2,4-dienone)iron 以 四氢呋喃 、 乙醚 、 水 为溶剂， 以82%的产率得到
  参考文献：
  名称：

  Demetalation of Tricarbonyl(cyclopentadienone)iron Complexes Initiated by a Ligand Exchange Reaction with NaOH—X-Ray Analysis of a Complex with Nearly Square-Planar Coordinated Sodium

  摘要：

  A sequential exchange of one carbonyl ligand by a hydrido ligand with NaOH, and then by an iodo ligand with iodopentane and finally treatment with acid transforms tricarbonyl(η4-cyclopentadienone)iron complexes into dicarbonyl(η5-hydroxycyclopentadienyl)iodoiron complexes. These iodo complexes demetalate with high selectivity to the corresponding free ligands on contact with air in daylight. Under basic reaction conditions at the stage of the iodo complex an anionic dicarbonyl(η4-cyclopentadienone)iodoiron complex is generated, which is dimeric in the solid state and has an almost square-planar arrangement of the ligands at the sodium counterion.

  DOI：

  10.1002/(sici)1521-3773(19990712)38:13/14<2064::aid-anie2064>3.0.co;2-w