1H-Imidazolium, 1-methyl-3-propyl-, chloride | 79917-89-8

• 物质功能分类: 有机原料 - 杂环化合物
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑啉类
• 英文名称: 1H-Imidazolium, 1-methyl-3-propyl-, chloride
• 英文别名: 1-methyl-3-propyl-1,2-dihydroimidazol-1-ium;chloride
• CAS: 79917-89-8
• 化学式: C7H15ClN2
• 分子量: 162.66
• InChiKey: GYTJXQRCNBRFGU-UHFFFAOYSA-N

物化性质

• 熔点：
  64 °C
• 溶解度：
  溶于甲醇

计算性质

• 辛醇/水分配系数(LogP)：
  1.49
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  6.5
• 氢给体数：
  1
• 氢受体数：
  2

安全信息

• 危险性防范说明：
  P264,P280,P302+P352+P332+P313+P362+P364,P305+P351+P338+P337+P313
• 危险性描述：
  H315,H319

文献信息

• Method for Preparing P-Hydroxycinnamate by Using Ionic Liquid for Catalytic Lignin Depolymerization
  申请人：South China University of Technology

  公开号：US20200181058A1

  公开（公告）日：2020-06-11

  The present invention discloses a method for preparing p-hydroxycinnamate by using an ionic liquid for catalytic lignin depolymerization comprising: 1) preparation of a halogen metal-based ionic liquid: preparing the halogen metal-based ionic liquid by reacting an alkylimidazole chloride with a metal chloride by heating the same to 30° C. to 80° C. with stirring; and 2) catalytic depolymerization of lignin: mixing the halogen metal-based ionic liquid and lignin with an alcohol, and after N 2 replacement, heating the solution to 140° C. to 200° C. and reacting the solution for 4-8 h while stirring to prepare high value-added chemicals with p-hydroxycinnamate as a main product. The present invention has advantages of a simple process, mild conditions, environmental kindness, and high selectivity for a main product. The ionic liquid is simple in preparation, has a good atom economy, and is recyclable. Under optimal conditions, the yield of p-hydroxycinnamate can reach 40-80 mg/g.

  本发明公开了一种利用离子液体催化木质素裂解制备对羟基肉桂酸的方法，包括：1）制备卤金属基离子液体：将烷基咪唑氯化物与金属氯化物在30°C至80°C加热搅拌反应，制备卤金属基离子液体；2）木质素催化裂解：将卤金属基离子液体与木质素和醇混合，在氮气置换后，将溶液加热至140°C至200°C，搅拌反应4-8小时，制备以对羟基肉桂酸为主要产品的高附加值化学品。本发明具有工艺简单、条件温和、环保友好、主要产物选择性高的优点。该离子液体制备简单，原子经济性好，可循环利用。在最佳条件下，对羟基肉桂酸的产率可达40-80毫克/克。
• Method for preparing p-hydroxycinnamate by using ionic liquid for catalytic lignin depolymerization
  申请人：South China University of Technology

  公开号：US10807940B2

  公开（公告）日：2020-10-20

  The present invention discloses a method for preparing p-hydroxycinnamate by using an ionic liquid for catalytic lignin depolymerization comprising: 1) preparation of a halogen metal-based ionic liquid: preparing the halogen metal-based ionic liquid by reacting an alkylimidazole chloride with a metal chloride by heating the same to 30° C. to 80° C. with stirring; and 2) catalytic depolymerization of lignin: mixing the halogen metal-based ionic liquid and lignin with an alcohol, and after N2 replacement, heating the solution to 140° C. to 200° C. and reacting the solution for 4-8 h while stirring to prepare high value-added chemicals with p-hydroxycinnamate as a main product. The present invention has advantages of a simple process, mild conditions, environmental kindness, and high selectivity for a main product. The ionic liquid is simple in preparation, has a good atom economy, and is recyclable. Under optimal conditions, the yield of p-hydroxycinnamate can reach 40-80 mg/g.

  本发明公开了一种利用离子液体催化木质素解聚制备对羟基肉桂酸盐的方法，包括：1) 制备卤素金属基离子液体：通过将烷基咪唑氯化物与金属氯化物反应制备卤素金属基离子液体，方法是将卤素金属基离子液体加热至 30° C 至 80° C。2) 木质素的催化解聚：将卤素金属基离子液体和木质素与醇混合，置换 N2 后，将溶液加热至 140°C 至 200°C，搅拌反应 4-8 小时，制备以对羟基肉桂酸酯为主要产品的高附加值化学品。本发明具有工艺简单、条件温和、环保、主产品选择性高的优点。离子液体制备简单，原子经济性好，可回收利用。在最佳条件下，对羟基肉桂酸酯的产量可达 40-80 mg/g。
• [EN] METHOD FOR PREPARING 5-HYDROXYMETHYLFURFURAL<br/>[FR] PROCÉDÉ DE PRÉPARATION DE 5-HYDROXYMÉTHYLFURFURAL<br/>[ZH] 制备5-羟甲基糠醛的方法
  申请人：NINGBO INSTITUTE OF MATERIALS TECH & ENGINEERING CHINESE ACADEMY OF SCIENCES

  公开号：WO2021120476A1

  公开（公告）日：2021-06-24

  本申请公开了一种制备5-羟甲基糠醛的方法。该方法将六碳糖类化合物、离子液体和酸性催化剂直接进行混合得到混合物，反应过程中抽真空将水带走，得到5-羟甲基糠醛。该方法在温和条件下以离子液体作为溶剂来制备HMF的方法，在此发明中由于反应温度较低，基本无副反应发生，反应后溶液澄清透明，这为分子筛用于催化此反应提供了可能。
• IONIC LIQUID MEDIATED SOL-GEL SORBENTS
  申请人：Abdul Malik

  公开号：US20120128551A1

  公开（公告）日：2012-05-24

  Ionic liquid (IL)-mediated sol-gel hybrid organic-inorganic materials present enormous potential for effective use in analytical microextraction. One obstacle to materializing this prospect arises from high viscosity of ILs significantly slowing down sol-gel reactions. A method was developed which provides phosphonium-based, pyridinium-based, and imidazolium-based IL-mediated advanced sol-gel organic-inorganic hybrid materials for capillary microextraction. Scanning electron microscopy results demonstrate that ILs can serve as porogenic agents in sol-gel reactions. IL-mediated sol-gel coatings prepared with silanol-terminated polymers provided up to 28 times higher extractions compared to analogous sol-gel coatings prepared without any IL in the sol solution. This study shows that IL-generated porous morphology alone is not enough to provide effective extraction media: careful choice of the organic polymer and the precursor with close sol-gel reactivity must be made to ensure effective chemical bonding of the organic polymer to the created sol-gel material to be able to provide the desired sorbent characteristics.
• METHOD OF MAKING IONIC LIQUID MEDIATED SOL-GEL SORBENTS
  申请人：Malik Abdul

  公开号：US20140057048A1

  公开（公告）日：2014-02-27

  Ionic liquid (IL)-mediated sol-gel hybrid organic-inorganic materials present enormous potential for effective use in analytical microextraction. One obstacle to materializing this prospect arises from high viscosity of ILs significantly slowing down sol-gel reactions. A method was developed which provides phosphonium-based, pyridinium-based, and imidazolium-based IL-mediated advanced sol-gel organic-inorganic hybrid materials for capillary microextraction. Scanning electron microscopy results demonstrate that ILs can serve as porogenic agents in sol-gel reactions. IL-mediated sol-gel coatings prepared with silanol-terminated polymers provided up to 28 times higher extractions compared to analogous sol-gel coatings prepared without any IL in the sol solution. This study shows that IL-generated porous morphology alone is not enough to provide effective extraction media: careful choice of the organic polymer and the precursor with close sol-gel reactivity must be made to ensure effective chemical bonding of the organic polymer to the created sol-gel material to be able to provide the desired sorbent characteristics.