4,4'-[Oxydi(ethane-2,1-diyl)]bis(2,6-dimethylmorpholine) | 103251-80-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 恶嗪烷类
• 英文名称: 4,4'-[Oxydi(ethane-2,1-diyl)]bis(2,6-dimethylmorpholine)
• 英文别名: 4-[2-[2-(2,6-dimethylmorpholin-4-yl)ethoxy]ethyl]-2,6-dimethylmorpholine
• CAS: 103251-80-5
• 化学式: C₁₆H₃₂N₂O₃
• 分子量: 300.44
• InChiKey: XDGWKBYFXMRODP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  21
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  34.2
• 氢给体数：
  0
• 氢受体数：
  5

文献信息

• Non-fraying substrate for use in an orthopaedic casting bandage and a process for its preparation
  申请人：SMITH AND NEPHEW CASTINGS INC.

  公开号：EP0286426A1

  公开（公告）日：1988-10-12

  A resin-coated, knitted glass fibre substrate is prevented from fraying at a cut end by the presence at the said cut end of a polymer strip. The substrate is preferably coated with a water curable resin whereby the coated substrate can be used as an orthopaedic bandage. Processes for applying the polymer strip to the resin-coated substrate are also described.

  一种涂有树脂的针织玻璃纤维基材，由于在其剪切端的聚合物条的存在而不会在剪切端磨损。基材上最好涂有水固化树脂，这样涂过树脂的基材就可以用作矫形绷带。此外，还介绍了将聚合物条涂在涂有树脂的基材上的工艺。
• Orthopaedic splinting material
  申请人：SMITH & NEPHEW plc

  公开号：EP0295031A2

  公开（公告）日：1988-12-14

  Compounds of the formula (I):     R¹-(OCH₂CH₂)n-O-CO-(NH)m-R²      (I) are provided wherein R¹ is an alkyl group of 1 to 14 carbon atoms, a phenyl group, a phenyl group substituted by an alkyl group of 1 to 12 carbon atoms or an alkyl group of 1 to 4 carbon atoms substituted by a phenyl group; R² is an alkyl group of 1 to 14 carbon atoms, a phenyl group, a phenyl group substituted by an alkyl group of 1 to 12 carbon atoms or an alkyl group of 1 to 4 carbon atoms substituted by a phenyl group; n is 6 to 100; and m is 0 or 1. Such compounds and those of the formula     R¹-X-(OCH₂CH₂)n-O-CO-(NH)m-R² wherein R¹, R², m and n are as defined above and X is a bond or (NH)m-CO-group may be dissolved in an amount of from 1 to 10% by weight in an isocyanate resin to form a water curable composition suitable as low tack orthopaedic splinting material when coated onto a suitable substrate.

  式 (I) 的化合物： R¹-(OCH₂CH₂)n-O-CO-(NH)m-R²(I) 其中 R¹ 是 1 至 14 个碳原子的烷基、苯基、被 1 至 12 个碳原子的烷基取代的苯基或被苯基取代的 1 至 4 个碳原子的烷基；R² 是 1 至 14 个碳原子的烷基、苯基、被 1 至 12 个碳原子的烷基取代的苯基或被苯基取代的 1 至 4 个碳原子的烷基；n 是 6 至 100；m 是 0 或 1。此类化合物和式 R¹-X-(OCH₂CH₂)n-O-CO-(NH)m-R² 其中 R¹、R²、m 和 n 如上文所定义，X 为键或 (NH)m-CO 基团，可以以 1-10%（重量比）的量溶解在异氰酸酯树脂中，形成水固化组合物，涂覆在合适的基底上，可用作低粘性矫形夹板材料。
• Bandages
  申请人：SMITH & NEPHEW P.L.C.

  公开号：EP0326285A2

  公开（公告）日：1989-08-02

  A knitted substrate suitable for use in a resin-coated, water-hardenable orthopaedic splinting bandage is described. The substrate comprises inelastic fibres being incorporated in the substrate in the length direction. In a preferred substrate the low modulus fibre is a multifilament polypropylene and the elastic fibre is a polyurethane yarn. Conformable orthopaedic bandages employing the substrate are also described.

  本文描述了一种适用于树脂涂层水硬性矫形夹板绷带的针织基材。基材包括沿长度方向编入基材的非弹性纤维。在一种优选基材中，低模量纤维为多丝聚丙烯，弹性纤维为聚氨酯纱。此外，还介绍了采用这种基材的可变形矫形绷带。
• Bookbinding applications utilizing warm melt polyurethanes
  申请人：H.B. Fuller Licensing & Financing, Inc.

  公开号：EP0813979A2

  公开（公告）日：1997-12-29

  Reactive hot melt polyurethane adhesives are useful for use in the graphic arts area, and in particular, for bookbinding applications such as casemaking, casing-in, gluing-off or thread-securing, facing, slip cases, lining-up, tightbacking, and bonding sides and joints; and for puzzle and gameboard lamination.

  反应型热熔聚氨酯粘合剂适用于制版印刷领域，特别是书籍装帧应用，如制版、装盒、粘合或螺纹固定、封面、滑套、衬垫、紧固、粘合侧边和接缝，以及拼图和游戏板层压。
• A photocurable resin composition and a method for producing the same
  申请人：TAKEDA CHEMICAL INDUSTRIES, LTD.

  公开号：EP0849296A2

  公开（公告）日：1998-06-24

  The invention provides a photocurable resin composition which inhibits the deactivation of a bisacylphosphine oxide-series photopolymerization initiator and is useful for coating optical fibers. The photocurable resin composition comprises (A) a polyurethane (meth)acrylate oligomer, (B) an ethylenically unsaturated compound, (C) a bisacylphosphine oxide-series photopolymerization initiator, and (D) a tertiary amine and no tin component. Incorporation of the component (D) inhibits the decomposition and deactivation of the component (C). The component (A) may contain an aliphatic C14-40 polyol (hydrogenated dimerdiol, 12-hydroxystearyl alcohol) as a polyol component. This resin composition is used for a primary coating of a glass fiber or an indirect coating of an optical fiber through the primary layer, the coating layer being cured by light irradiation to provide an optical fiber coated with the resin composition.

  本发明提供了一种光固化树脂组合物，可抑制双酰氧化膦系列光聚合引发剂的失活，并可用于光纤涂层。这种光固化树脂组合物包括：(A) 一种聚氨酯（甲基）丙烯酸酯低聚物；(B) 一种乙烯基不饱和化合物；(C) 一种双基氧化膦系列光聚合引发剂；(D) 一种叔胺和无锡成分。组分（D）的加入可抑制组分（C）的分解和失活。组分（A）可含有脂肪族 C14-40 多元醇（氢化二聚二醇、12-羟基硬脂醇）作为多元醇组分。这种树脂组合物可用于玻璃纤维的初级涂层或通过初级涂层对光纤进行间接涂层，涂层通过光照射固化，从而得到涂有该树脂组合物的光纤。