(pyridine)(tetraphenylporphyrinato)manganese(II) | 57034-31-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: (pyridine)(tetraphenylporphyrinato)manganese(II)
• 英文别名: manganese(II)tetraphenylporphine(pyridine)；Mn(II)(meso-tetraphenylporphyrinato)(py)；MnTPP(py)
• CAS: 57034-31-8
• 化学式: C₄₉H₃₃MnN₅
• 分子量: 746.773
• InChiKey: HCEFOURCEDOCKM-YKKPBKTHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (pyridine)(tetraphenylporphyrinato)manganese(II) 以 neat (no solvent) 为溶剂， 生成 2,3,5,7-四苯基-21H,23H-卟吩锰(2+)盐(1:1)
  参考文献：
  名称：

  Urban, Marek W.; Nakamoto, Kazuo; Basolo, Fred, Inorganic Chemistry, 1982, vol. 21, # 9, p. 3406 - 3408

  摘要：

  DOI：
• 作为产物：
  描述：

  吡啶 、 Mn(meso-tetraphenylporphyrinatodianion)(η1-ONO) 以 甲苯 为溶剂， 生成 (pyridine)(tetraphenylporphyrinato)manganese(II)
  参考文献：
  名称：

  Hoshino, Mikio; Nagashima, Yutaka; Seki, Hiroshi, Inorganic Chemistry, 1998, vol. 37, # 10, p. 2464 - 2469

  摘要：

  DOI：

文献信息

• Solvent Dependence of the Structure and Magnetic Ordering of Ferrimagnetic Manganese(III) <i>meso</i>-Tetraphenylporphyrin Tetracyanoethenide, [MnTPP]⁺[TCNE]^•^-·<i>x</i>(solvent). Evidence for Orientationally Disordered [TCNE]^•^-
  作者：Wendy Hibbs、Durrell K. Rittenberg、Ken-ichi Sugiura、Brian M. Burkhart、Brian G. Morin、Atta M. Arif、Louise Liable-Sands、Arnold L. Rheingold、Muttaiya Sundaralingam、Arthur J. Epstein、Joel S. Miller

  DOI：10.1021/ic0011922

  日期：2001.4.1

  All form 1-D chain structures with intrachain Mn.Mn separations ranging from 9.202 to 10.218 A. The 173 K crystal structure of [MnTPP][TCNE].2PhMe has been rerefined, revealing that the [TCNE](*)(-) is 2-fold-disordered and coordinated to Mn(III) by a pair of trans cyano nitrogen atoms to form parallel one-dimensional chains. The two orientations of [TCNE](*)(-) are related by a 180 degrees rotation

  四苯基卟啉锰酸酯（III）四氰基乙烯，[MnTPP] [TCNE]是不断增长的线性链（1-D）配位聚合物的原型，这些配体磁性排列为亚铁。[MnTPP] [TCNE] .xS [S = PhMe（x = 2），1,2-C（6）H（4）Me（2）（x = 1），1,2-C（6）H（ 4）Cl（2）（x = 3），1,2,4-C（6）H（3）Cl（3）（x = 2）和1,3-C（6）H（4）Cl （2）（x = 2）]已经制备并在结构和磁学上进行了表征。均形成1-D链结构，链内Mn.Mn分离范围为9.202至10.218A。[MnTPP] [TCNE] .2PhMe的173 K晶体结构已被精制，表明[TCNE]（*）（-）是2倍无序，并通过一对反式氰基氮原子与Mn（III）配位以形成平行的一维链。[TCNE]（*）（-）的两个方向通过绕对角轴旋转180度而关联，该对角轴连接与Mn（III）结合的反式氮原子。主要形式的占有率为83
• Synthesis and Magnetic Exchange Properties of Linear Trinuclear Oxo-Bridged MIIIORuIVOMIII Complexes (M = Fe, Cr, Mn) Formed by Two-Electron Redox Reactions
  作者：Kevin J. Berry、Boujemaa Moubaraki、Keith S. Murray、Peter J. Nichols、Lewis D. Schulz、Bruce O. West

  DOI：10.1021/ic00120a017

  日期：1995.8

  The two-electron reductions of various porphyrin complexes Ru-VI(O)(2)(P) by Fe(II), Cr(II), and Mn(II) compounds of porphyrins and salicylaldimines result in the formation of heterotrimetallic ore-bridged complexes (L)M(III)-ORuIV(P)OM(III)(L) (M = Fe(III), Cr(III), Mn(III); P is the dianion of 5,10,15,20-tetraarylporphyrins, such as tetraphenylporphyrin (TPP), tetrakis(p-methoxyphenyl)porphyrin (TMP), or 2,3,7,8,12,13,17,18-octaethylporphyrin (OEP); L is TPP, TMP, or OEP or the dianions of N,N'-(4-methyl-4-azaheptane-1,7-diyl)bis(salicylaldimine) (salmah) or N,N'-ethane-1,2-diylbis(salicylaldimine) (salen). A detailed study of the temperature- and field-dependent magnetic properties of this rather novel series of (L)M(III)ORu(IV)(P)OM(III)(L) compounds has been made. The spin-states of the constituent metal centers are as follows: Ru-IV, S-Ru = 1 (d(4)); Fe-III S-Fe = 5/2 (d(5)); Cr-III, S-Cr = 3/2 (d(3)); Mn-III, S-Mn = 4/2 (d(4)). The spin-state and coordination geometry of the (L)Fe-III groups were confirmed by Mossbauer spectral measurements. Trinuclear combinations of the present kind give rise to unusual coupled spin-state energy levels which, in the case of (L)(FeORuIV)-O-III(P)OFeIII(L) compounds, result in ''ferromagnetic-like'' plots of magnetic moment versus temperature, particularly at low temperatures. The following best-fit values of parameters were deduced from the magnetic moment data, obtained in 1 T fields over the temperature range 4.2-300 K. (salmah)FeORu(TPP)OFe(salmah): g = 1.97, J(12) = -19.7 cm(-1), J(13) = +6.5 cm(-1), alpha J(13)/J(12) = -0.33, ground-state S = 4; (TMP)FeORu(TPP)OFe(TMP): g = 1.95, J(12) = -23.4 cm(-1), J(13) = 5.4 cm(-1), alpha = -0.23, ground-state S = 4. (TPP)FeORu(TPP)OFe(TPP): g = 2.0, J(12) = -35.7 cm(-1), J(13) = 11.2 cm(-1), alpha = -0.31, ground-state S = 4, [(TPP)Fe]O-2 impurity = 13%, zero-field splitting of the S = 4 state (D cm approximate to 5 cm(-1)). (TMP)MnORu(TPP)OMn(TMP): g = 1.93, J(12) = -17.4 cm(-1), J(13) = 9.6 cm(-1), alpha = -0.55, groundstate S = 3. (TPP)CrORu(TPP)OCr(TPP): g = 1.98, J(12) = -25.3 cm(-1), J(13) = -11.1 cm(-1), alpha = 0.44, groundstate S = 1. Possible reasons for the small sizes of the J(12) values, in comparison to those of related M(III)OM(III) and (RuORuIV)-O-IV compounds, are discussed.
• Perrée-Fauvet; Gaudemer; Bonvoisin, Inorganic Chemistry, 1989, vol. 28, # 18, p. 3533 - 3538
  作者：Perrée-Fauvet、Gaudemer、Bonvoisin、Girerd、Boucly-Goester、Boucly

  DOI：——

  日期：——
• Stabilization of Magnetic Ordering Observed for the Bridging NCN Group
  作者：Jordan L. Arthur、Curtis E. Moore、Arnold L. Rheingold、Joel S. Miller

  DOI：10.1021/ic200083j

  日期：2011.4.4

  The reaction of meso-tetraphenylporphyrina: tomanganese(II) (MnTPP) and. N,7,7-tricyanoquinomethanimine (TCQMI) forms [(MnTPP)-T-III](+)}(2)[TCQMI](2)(2-), which possesses a one-dimensional chain with mu(1,3)-NCN linkages. The reduced [TCQMI](center dot-) dimerizes as [TCQMI](2)(2-) with a long, central 1.611(8) angstrom C-C bond and leads to a honeycomb, two-dimensionally layered structure with 24-membered rings. The mu(1,3)-NCN linkage stabilizes a canted antiferromagnetic (weak ferromagnetic) behavior with T-c of 3.7 K.