| 742098-01-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• CAS: 742098-01-7
• 化学式: C₄₅H₆₈Co₂N₁₀O₁₁
• 分子量: 1043.08
• InChiKey: MVHAOHBLBDCRJV-PWBDMXEWSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (pyridine)((CH2)6Br)cobaloxime 、 3,5-二羟基苯甲醇 在 K₂CO₃ 、 18-crown-6 作用下， 以 丙酮 为溶剂， 以45%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of cobaloxime dendrimer precursors

  摘要：

  Reactions of bromobutyl or bromohexyl cobaloxime complexes with 3,5-dihydroxybenzyl alcohol in the presence of potassium carbonate gave, in both cases, mono- and di-cobalt complexes. These complexes were characterized largely by their NMR spectra. In addition, a new dimeric alkylcobaloxime complex was formed in these reactions by HBr elimination from the bromoalkyl complexes. This dimer was fully characterized and its X-ray crystal structure was determined. A zero generation dendrimer containing three cobaloxime groups was obtained by reaction of the bromobutyl cobaloxime with the core molecule 1,1,1-tris(4-hydroxyphenyl)ethane. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.01.043