bis(4N-(methylamino)pent-3-en-2-onato)Copper(II) | 15225-84-0

• 分子结构分类: 有机化合物
• 英文名称: bis(4N-(methylamino)pent-3-en-2-onato)Copper(II)
• CAS: 15225-84-0
• 化学式: C₁₂H₂₀CuN₂O₂
• 分子量: 287.849
• InChiKey: MXDZKWYAZOVGFT-XXXYRMOLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4-(methylamino)-3-penten-2-one 、 copper hydroxide 在 sodium hydroxide 作用下， 以 丙酮 为溶剂， 以80%的产率得到bis(4N-(methylamino)pent-3-en-2-onato)Copper(II)
  参考文献：
  名称：

  Structure of bis-(1,1,1-trifluoro-2-(methylimino)pentanoato-4)copper(II). Thermal properties of N-methylsubstituted copper(II) β-iminoketonates

  摘要：

  The single crystal X-ray diffraction (XRD) method was used to determine the structure of the [Cu(mi-tfac)(2)] (mi-tfac = MeC(O)CHC(NMe)CF3) complex at the temperature of 150 K. The crystallographic data are as follows: space group Pnna, a = 11.8798(16) , b = 12.0315(16) , c = 10.6259(14) , V = 1518.8(4) (3), Z = 4, R = 0.0288. The structure is molecular, the coordination environment of copper in the molecule adopts a distorted tetrahedral geometry. The Cu-O and Cu-N distances are 1.9182(13) and 1.9610(16) respectively, the OCuN chelate angle is 94.18(5)A degrees. The thermal properties of the compounds [Cu(mi-tfac)(2)] and [Cu(RC(O)CHC(NMe)R)(2)] (R = Me, (t) Bu) in the condensed phase have been studied by the methods of thermogravimetry and differential scanning calorimetry. The thermodynamic characteristics of the melting processes have been determined.

  DOI：

  10.1134/s0022476615080144