Bis(3-hydroxypropyl) nonanedioate | 74623-98-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Bis(3-hydroxypropyl) nonanedioate
• CAS: 74623-98-6
• 化学式: C₁₅H₂₈O₆
• 分子量: 304.38
• InChiKey: LHZBAWPKOKCSKV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  21
• 可旋转键数：
  16
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.87
• 拓扑面积：
  93.1
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  己二酸 、 methyloxirane 、 Bis(3-hydroxypropyl) nonanedioate 、 、 、 生成 Bis-(hydroxypropyl) adipate
  参考文献：
  名称：

  Coating compositions including oligomeric hydroxy phosphate catalyst-d

  摘要：

  一种改进的热固性涂层组合物，包括成膜成分和氨基化合物，其中组合物通过氨基化合物与成膜材料上存在的羟基官能团之间的反应固化。改进包括在组合物中包括催化剂，该催化剂包括至少一种寡聚羟基官能有机磷酸酯，所述有机磷酸酯选自某些磷酸的单酯和双酯。

  公开号：

  US04215204A1

文献信息

• High solids coating composition with oligomeric hydroxyphosphate
  申请人：Ford Motor Company

  公开号：US04178319A1

  公开（公告）日：1979-12-11

  A fast curing, high solids coating composition which upon curing forms a hard, glossy, durable coating exhibiting excellent resistance to solvents and water. The coating composition which is particularly adapted for use as an automotive topcoat, contains greater than about 60 percent by weight of nonvolatile solids and, exclusive of pigments, solvents and other nonreactive components, consists essentially of: (A) a polyepoxide resin having a number average molecular weight (M.sub.n) of between about 140 and about 3,000; (B) a reactive catalyst comprising at least one oligomeric hydroxy functional organophosphate ester selected from certain mono- and diesters of phosphoric acid; (C) an amine-aldehyde crosslinking agent; and (D) optionally, a hydroxy functional additive. The oligomeric hydroxy functional organophosphate ester is included in the composition in an amount sufficient to provide between about 0.8 and about 1.5 equivalents of acid functionality for each equivalent of epoxy functionality in the polyepoxide resin and the amino crosslinking agent is included in the composition in an amount sufficient to provide at least about 0.4 equivalents of nitrogen crosslinking functionality for each equivalent of hydroxy functionality included in the composition.

  一种快速固化、高固体含量的涂料组合物，固化后形成一层坚硬、光亮、耐溶剂和水的耐久涂层。该涂料组合物特别适用于用作汽车面漆，其含有大于约60%的非挥发性固体，并且除了颜料、溶剂和其他非反应性成分外，基本上由以下组成：（A）聚环氧树脂，其数平均分子量（M.sub.n）在约140至约3,000之间；（B）反应性催化剂，包括至少一种选择自磷酸的某些单酯和二酯的寡聚羟基有机磷酸酯；（C）胺醛交联剂；（D）可选的羟基功能添加剂。寡聚羟基有机磷酸酯的含量足以为聚环氧树脂中的每个环氧功能提供约0.8至约1.5当量的酸功能，并且氨交联剂的含量足以为组合物中包含的每个羟基功能提供至少约0.4当量的氮交联功能。
• High solids coating composition with oligomeric hydroxy phosphate
  申请人：Ford Motor Company

  公开号：US04178324A1

  公开（公告）日：1979-12-11

  A fast curing, high solids coating composition which upon curing forms a hard, glossy, durable coating exhibiting excellent resistance to solvents and water. The coating composition which is particularly adapted for use as an automotive topcoat, contains greater than about 60 percent by weight of nonvolatile solids and, exclusive of pigments, solvents and other nonreactive components, consists essentially of: (A) a bifunctional copolymer bearing hydroxy functionality and pendent epoxy functionality, having a number average molecular weight (M.sub.n) of between about 1500 and about 10,000 and a glass transition temperature (Tg) of between about -25.degree. C. and about 70.degree.; (B) a reactive catalyst comprising at least one oligomeric hydroxy functional organophosphate ester selected from certain mono- and diesters of phosphoric acid; (C) an amine-aldehyde crosslinking agent; and (D) optionally, a hydroxy functional additive. The oligomeric hydroxy functional organophosphate ester is included in the composition in an amount sufficient to provide between about 0.8 and about 1.5 equivalents of acid functionality for each equivalent of pendent epoxy functionality in copolymer (A), and the amine aldehyde crosslinking agent is included in the composition in an amount sufficient to provide at least about 0.4 equivalents of nitrogen crosslinking functionality for each equivalent of hydroxy functionality included in the composition.

  一种快速固化、高固体份涂层组合物，固化后形成一种坚硬、光泽、耐溶剂和水的持久涂层。该涂层组合物特别适用于用作汽车面漆，含有大于约60％的非挥发性固体份，除颜料、溶剂和其他非反应性成分外，基本上由以下组成：（A）一种具有羟基功能和悬挂环氧功能的双官能团共聚物，其数均分子量（M.sub.n）介于约1500和约10000之间，玻璃转移温度（Tg）介于约-25℃和约70℃之间；（B）至少一种寡聚羟基功能有机磷酸酯反应催化剂，选自某些磷酸的单酯和双酯；（C）胺-醛交联剂；以及（D）可选的羟基功能添加剂。寡聚羟基功能有机磷酸酯以足够的量包含在组合物中，以为共聚物（A）中的每个悬挂环氧功能提供约0.8到约1.5当量的酸功能，并且胺醛交联剂以足够的量包含在组合物中，以为组合物中包含的每个羟基功能提供至少约0.4当量的氮交联功能。
• Thermosetting composition
  申请人：FORD MOTOR COMPANY LIMITED

  公开号：EP0032054A2

  公开（公告）日：1981-07-15

  Two component compositions particularly useful as high solids thermosetting coating compositions and molding compositions. Compositions comprise a first component comprising an oligomeric hydroxy functional phosphate ester prepared by reaction of a polyepoxide and an acid phosphate ester; and a second component comprising a isocyanate cross-linking agent.

  双组分组合物特别适用于高固体热固性涂料组合物和模塑组合物。组合物包括第一组份和第二组份，第一组份包括通过聚环氧化物和酸性磷酸酯反应制备的低聚羟基官能磷酸酯；第二组份包括异氰酸酯交联剂。
• Coating composition
  申请人：Ford Motor Company Limited

  公开号：EP0029339A1

  公开（公告）日：1981-05-27

  A fast curing, coating composition that is adapted for use as an automotive topcoat and which upon curing forms a hard, glossy, durable coating exhibiting excellent resistance to solvents and water. The coating composition which may contain greater than about 55 percent by weight of nonvolatile solids and, exclusive of pigments, solvents and other nonreactive components, consists essentially of: (A) a bifunctional copolymer bearing hydroxy functionality and pendent epoxy functionality, having a number average molecular weight (Mn) of between about 1500 to about 10.000 and a glass transition temperature (Tg) of between about -25° to about 70°; (B) a reactive catalyst comprising at least one phosphonic acid derivative; (C) an amino resin crosslinking agent; and (D) optionally, a hydrcxy functional additive. The phosphonic acid derivative catalyst is ncluded in the composition in an amount sufficient to provide between about 8 to about 1.4 equivalents of acid functionality in copolymer (A), and the amino resin crosslinking agent is Included in the composition in an amount sufficient to provide at least about .4 equivalents of nitrogen crosslinking functionality for each equivalent of hydroxy functionality included in the composition.

  一种快速固化的涂料组合物，可用作汽车面漆，固化后可形成坚硬、光亮、耐久的涂层，具有优异的耐溶剂性和抗水性。该涂料组合物的非挥发性固体含量按重量计可超过 55%，除颜料、溶剂和其他非反应性成分外，主要由以下成分组成： (A) 含有羟基官能团和下垂环氧官能团的双官能团共聚物，其平均分子量 (Mn) 在约 1500 到约 10.000 之间，玻璃化温度 (Tg) 在约 -25° 到约 70° 之间； (B) 由至少一种膦酸衍生物组成的活性催化剂； (C) 一种氨基树脂交联剂；以及 (D) 可选的水合官能添加剂。 膦酸衍生物催化剂在组合物中的用量足以在共聚物（A）中提供约 8 至约 1.4 个当量的酸官能度，氨基树脂交联剂在组合物中的用量足以为组合物中的每一个当量的羟基官能度提供至少约 0.4 个当量的氮交联官能度。
• Coating compositions containing an hydroxy functional organophosphate ester
  申请人：FORD MOTOR COMPANY LIMITED

  公开号：EP0013824B1

  公开（公告）日：1983-06-22