| 150882-43-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• CAS: 150882-43-2
• 化学式: C₂₂H₄N₁₄Pd
• 分子量: 570.788
• InChiKey: FGSBEIHUFJJFTN-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  sodium salt of 1,1,2-tricyano-2-(3,4-dicyano-5-imino-2,5-dihydro-1H-pyrrol-2-ylidene) ethanide 、 sodium hexachlorodipalladate(II) 以 四氢呋喃 为溶剂， 生成 、
  参考文献：
  名称：

  Solution studies of the reaction between the pyrrolenine anion 1,2,-tricyano-2-(3,4-dicyano-5-imino-2,5-dihydro-1H-pyrrol-2-ylidene)ethanide and palladium(II) chlorides. Formation and characterization of the mono β-diimino-tetracyano-pyrrolizinido-palladium(II) complex

  摘要：

  The metal-assisted isomerization of the pyrrolenine anion 1,1,2-tricyano-2-(3,4-dicyano-5-imino-2,5-dihydro-1H-pyrrol-2-ylidene)ethanide (C11N7H2-, L') to the 1,2,6,7-tetracyano-3,5-diimino-2,5-dihydro-pyrrolizinide anion (L) has been studied in solutions of CH2Cl2 or tetrahydrofuran (THF) with the palladium(II) chlorides, PdCl42- or Pd2Cl62-, respectively. In THF the bis-chelate PdL(2) and the mono-chelate PdLCl(2)(-) are formed. In CH2Cl2, only mono-chelate species are formed such as PdLCl(2)(-) or PdLCl(CN)(-). The mono-chelate species show an optical spectrum, due to the drop PdL chromophore, qualitatively more similar to that of the corresponding phthalocyanine, PdPc, than that of PdL(2).

  DOI：

  10.1016/0277-5387(95)00230-p