1,8,15,22-tetraaminophthalocyanatocopper (II) | 15738-59-7

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: 1,8,15,22-tetraaminophthalocyanatocopper (II)
• 英文别名: copper(II) 1,8,15,22-tetraaminophthalocyanine；copper(II) 3,3',3'',3'''-tetraamino phthalocyanine；Copper(II) 1,8,15,22-tetra(amino)phthalocyanine；copper;2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13(18),14,16,19(39),20,22(27),23,25,28,30(37),31(36),32,34-nonadecaene-5,14,23,32-tetramine
• CAS: 15738-59-7
• 化学式: C₃₂H₂₀CuN₁₂
• 分子量: 636.137
• InChiKey: PUOMENLQXODTPZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.45
• 重原子数：
  45
• 可旋转键数：
  0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  180
• 氢给体数：
  4
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  1,8,15,22-tetraaminophthalocyanatocopper (II) 在 盐酸 、 sodium nitrite 、 copper(l) chloride 作用下， 生成 C32H12Cl4CuN8, β
  参考文献：
  名称：

  Synthesis, spectral and magnetic susceptibility studies on tetrachloro metal(II)phthalocyanines

  摘要：

  The present paper describes a simple method for the synthesis of symmetrically substituted 1,8,15,22-tetrachloro phthalocyanines of copper, cobalt, nickel and zinc. The title complexes are synthesized from the corresponding tetraamino metal phthalocyanines by modified Sandmeyers method and in turn the tetraamino metal phthalocyanines are prepared from 3-nitrophthalic acid. The bluish-green coloured tetrachloro metal phthalocyanine complexes are characterized by elemental, electronic, IR, magnetic susceptibility and X-ray powder diffraction studies to check the purity and the structural integrity. The magnetic susceptibility studies revealed that, the experimental values are higher than that of the spin only value magnetic moment, and the presence of intermolecular co-operative effects. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2005.05.012
• 作为产物：
  描述：

  3-硝基邻苯二甲酸 在 (NH₄)6Mo₇O₂₄ 、 NH₄Cl 、 sodium sulfide nonahydrate 作用下， 以 水 、 硝基苯 为溶剂， 生成 1,8,15,22-tetraaminophthalocyanatocopper (II)
  参考文献：
  名称：

  Synthesis, structural investigations and biological studies on symmetrically substituted 3,3′,3",3"′-tetra-methoxyphenylimino phthalocyanine complexes

  摘要：

  The present paper describes the synthesis and characterization of novel metal (II) 3,3',3aEuro(3),3aEuro '-tetramethoxyphenylimino substituted phthalocyanines (M-MeOPhImPcs) of copper (II), cobalt (II), nickel (II) and zinc (II) by condensing the 3,3',3aEuro(3),3aEuro(3)aEuro(2)-tetra amino phthalocyanines with anisaldehyde. The dark bluish green colored tetraimino substituted phthalocyanine derivatives were characterized by various physico-chemical techniques like elemental analysis, magnetic susceptibility, electronic, IR, powder X-ray diffraction and thermo gravimetric analysis (TGA) to check the structural integrity and purity. The variations of magnetic moment as a function of field strength indicated the presence of inter molecular co-operative interactions. The complexes were also evaluated for their antifungal and antibacterial activities.

  DOI：

  10.1134/s0036023608010117

文献信息

• Mikhalenko, S. A.; Solov'eva, L. I.; Ivanova, T. M., Journal of general chemistry of the USSR, 1985, vol. 55, p. 986 - 989
  作者：Mikhalenko, S. A.、Solov'eva, L. I.、Ivanova, T. M.、Luk'yanets, E. A.

  DOI：——

  日期：——
• TURKER, LEMI;OKER, LEVENT, DYES AND PIGM., 13,(1990) N, C. 81-92
  作者：TURKER, LEMI、OKER, LEVENT

  DOI：——

  日期：——
• KATAI, SYUNDZI;FUKUMOTO, YUDZI
  作者：KATAI, SYUNDZI、FUKUMOTO, YUDZI

  DOI：——

  日期：——