trans-{CoCl2enC3H10N2}Cl | 98047-58-6

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: trans-{CoCl2enC3H10N2}Cl
• 英文别名: ethane-1,2-diamine;propane-1,3-diamine;trichlorocobalt
• CAS: 98047-58-6
• 化学式: C₅H₁₈Cl₂CoN₄*Cl
• 分子量: 299.577
• InChiKey: RPMXIPFJTHNSSX-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-{CoCl2enC3H10N2}Cl 在 propylenediamine 、 KI 作用下， 以 水 为溶剂， 生成 Co(ethylenediamine)(propylenediamine)(trimethylenediamine)I3
  参考文献：
  名称：

  Syamal, A.; Mandal, P. K., Journal of the Indian Chemical Society, 1980, vol. 57, p. 100 - 102

  摘要：

  DOI：
• 作为产物：
  描述：

  盐酸 、 trans-{Co(NO2)2enC3H10N2}NO2 以 盐酸 为溶剂， 生成 trans-{CoCl2enC3H10N2}Cl
  参考文献：
  名称：

  Some Coördination Compounds of Cobalt Containing Trimethylenediamine and Neopentanediamine

  摘要：

  DOI：

  10.1021/ja01206a024

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Co: SVol.B2, 123, page 583 - 585
  作者：

  DOI：——

  日期：——
• Synthesis and characterization of some new [Co(NN)2ACl]2+ [(NN) = bidentate amine, A = monoamine] complexes and a study of the role of the inert ligand “A” in controlling the rate of aquation of [Co(NN)2ACl]2+ complexes
  作者：S.K. Chawla、Alka、S.S. Sandhu

  DOI：10.1016/s0277-5387(00)83724-9

  日期：1992.1

  A series of new complexes of type (a) cis-[Co(en)(tn)ACl]Y [en = 1,2-diminoethane, tn = 1,3-diamino propane, A = NH, Me-NH2, Et-NH2, n-Bu-NH2, pyridine (py), beta and gamma-picoline (pic), imidazole (imz); Y = ZnCl42- or 2ClO4-] and (b) cis-[CO(tn)2ACl]Y [A = py, beta and gamma-pic, 1-Me-imz and 1,2-dimethyl-imidazole (Me2-imz)] have been prepared and characterized using UV-vis, C-13 NMR and elemental analysis. The kinetics of the release of chloride ions from some complexes in the aqueous acidic phase has been studied at 40 and 50-degrees-C. Both types of complexes showed similar rate constant values [k = 8.5 x 10(-5) to 1.77 x 10(-4) S-1 for type (a) and k = 6.85 x 10(-5) to 2.5 x 10(-4) s-1 for type (b)]. Indirect evidence for the existence of a distorted trigonal bipyramid (tbp) intermediate was obtained. The ability of the inert ligand ''A'' to control the rate of reaction by influencing the extent of distortion of square pyramid (sp) intermediate moiety (left after the removal of chloride) was demonstrated.
• SYAMAL A.; MANDAL P. K., J. INDIAN CHEM. SOC., 1980, 57, NO 1, 100-102
  作者：SYAMAL A.、 MANDAL P. K.

  DOI：——

  日期：——