[molybdenum(methoxide)5(acetonitrile)](heptachlorodibismutate) | 866396-16-9

• 英文名称: [molybdenum(methoxide)5(acetonitrile)](heptachlorodibismutate)
• CAS: 866396-16-9
• 化学式: Bi₂Cl₇*C₇H₁₈MoNO₅
• 分子量: 958.295
• InChiKey: GOEACRYOEZTYRG-UHFFFAOYSA-G

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  methanol,oxomolybdenum 、 氯化铋 、 乙腈 以 甲苯 、 乙腈 为溶剂， 以64%的产率得到[molybdenum(methoxide)5(acetonitrile)](heptachlorodibismutate)
  参考文献：
  名称：

  The structural characterization of the first mononuclear alkoxide cation: Isolation and X-ray study of [Mo(OMe)5(CH3CN)]Bi2Cl7

  摘要：

  Interaction of molybdenum oxomethoxide and bismuth chloride in toluene/acetonitrile media leads to the formation of an unusual ionic salt [MO(OMe)(5)(CH3CN)]Bi2Cl7 (1), providing the first example of an isolated mononuclear alkoxide cation, [Mo(OMe)(5)(CH3CN)](+) with rather uniform Mo-O(Me) bond lengths. The product can be isolated with moderate yields and only from solutions with considerable excess of the molybdenum reactant (Mo:Bi approximate to 2: 1) after refluxing of the reaction mixture, which indicates disproportionation of MoO(OMe)(4) in solution into MoO2(OMe)(2) and Mo(OMe)(6) as a crucial step in its formation. (C) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2005.03.006