palladium(II) 5,10,15-triphenyl-20-(4-hexadecanoxyphenyl)porphyrinate | 1029053-16-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: palladium(II) 5,10,15-triphenyl-20-(4-hexadecanoxyphenyl)porphyrinate
• CAS: 1029053-16-4
• 化学式: C₆₀H₆₀N₄OPd
• 分子量: 959.583
• InChiKey: BFFFWGMTNGUKNS-JRMDJUBSSA-N

反应信息

• 作为产物：
  描述：

  palladium dichloride 、 5-(4-hexadecyloxyphenyl)-10,15,20-triphenylporphine 以 further solvent(s) 为溶剂， 以80%的产率得到palladium(II) 5,10,15-triphenyl-20-(4-hexadecanoxyphenyl)porphyrinate
  参考文献：
  名称：

  Effect of the chemical modification of the tetrapyrrole macrocycle on the reactivity of porphyrins in complexation with Pt4+ and Pd2+ cations

  摘要：

  The reactions of 5,10,15,20-tetraphenylporpine, 5,10,15-triphenyl-20-(4-hexadecanoxyphenyl)porphine, 5,10,15,20-tetra-(4-butoxyphenyl)porphine, and 2,3,7,8,12,13,17,18-ocaethylporphine with H2PtCl6 in boiling phenol and with PdCl2 in boiling dimethylformamide are studied by spectrophotometry. Due to a strong electronic effect of the substituents, the reactivity of the tetrapyrrole macrocycle during porphyrinate formation changes by more than two orders of magnitude. Platinum(II) 5,10,15-triphenyl-20-(4-hexadecanoxyphenyl)porphinate and palladium(II) 5,10,15,20-tetra-(4-butoxyphenyl)porphinate have been synthesized and identified for the first time.

  DOI：

  10.1134/s0036023607020180