Cl(Et3P)2PtC(=NC6H4Me-p)C4H2SPt(PEt3)2Cl | 165194-52-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Cl(Et3P)2PtC(=NC6H4Me-p)C4H2SPt(PEt3)2Cl
• 英文别名: chloroplatinum(1+);N-(4-methylphenyl)-1-(2H-thiophen-2-id-5-yl)methanimine;triethylphosphane
• CAS: 165194-52-5；165307-29-9
• 化学式: C₃₆H₆₉Cl₂NP₄Pt₂S
• 分子量: 1132.98
• InChiKey: FNYAXAILOGSELL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  三乙基膦 以 四氢呋喃 、 二氯甲烷 、 1,2-二氯乙烷 为溶剂， 生成 Cl(Et3P)2PtC(=NC6H4Me-p)C4H2SPt(PEt3)2Cl 、 Cl(Et3P)2PtC(=NC6H4Me-p)C4H2SC(=NC6H4Me-p)Pt(PEt3)2Cl
  参考文献：
  名称：

  Insertion reaction of isocyanide into the PtC bonds of 2,5-thienylene-bridged diplatinum complexes and 2-thienyl platinum complexes: molecular structure of Cl(Et3P)2PtC(NC6H4OMe-p)C4H2SC (NC6H4OMe-p)Pt(PEt3)2Cl·CH2Cl2

  摘要：

  Treatments of 2,5-thienylene-bridged diplatinum complexes Cl(R(3)P)(2)PtC4H2SPt(PR(3))(2)Cl (1) with two equivalents of isocyanide cause the insertion of isocyanide into each of the two Pt-C bonds to produce Cl(R(3)P)(2)PtC(=NAr)C4H2SC(=NAr)-Pt(PR(3))(2)Cl (2). 2-Thienyl platinum complexes C4H3SPt(PR(3))(2)Cl (4) also react with isocyanide to give iminoacyl complexes C4H3SC(=NAr)Pt(PR(3))(2)Cl (5). Further insertion of isocyanide into Pt-C bonds of 2 and 5 was not observed even in the reaction with excess isocyanide. When 1a was treated with an equimolar amount of p-tolyl isocyanide, a single-insertion product Cl(Et(3)P)(2)PtC(=NC(6)H(4)Me-p)C4H2SPt(PEt(3))(2)Cl (3b) was obtained altogether with the mixture of 1a and 2a. The molecular structure of Cl(Et(3)P)(2)PtC(=NC(6)H(4)OMe-p)C4H2SC(=NC(6)H(4)OMe-p)Pt(PEt(3))(2)Cl . CH2Cl2 (2b) was determined by an X-ray crystallographic analysis and the crystallographic data are as follows: space group, P2(1)/n; a = 11.044(2), b = 28.086(3) and c = 18.396(3) Angstrom; beta = 93.96 degrees; V = 5692(2) Angstrom(3); Z = 4.

  DOI：

  10.1016/0022-328x(94)05193-f