| 957931-70-3

• 分子结构分类: 有机化合物 - 有机杂环化合物
• CAS: 957931-70-3
• 化学式: C₉₆H₁₃₆CuN₄O₁₆Si₄
• 分子量: 1778.04
• InChiKey: BLXAJHKWAUJDQD-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  tetrakis(acetonitrile)copper(I)tetrafluoroborate 、 Tri(propan-2-yloxy)-[3-[4-[9-[4-[3-tri(propan-2-yloxy)silylpropoxy]phenyl]-1,10-phenanthrolin-2-yl]phenoxy]propyl]silane 以 二氯甲烷 、 乙腈 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  Unexpected Coordination Chemistry of Bisphenanthroline Complexes within Hybrid Materials:  A Mild Way to Eu²⁺ Containing Materials with Bright Yellow Luminescence

  摘要：

  A hybrid organ ic-inorganic material containing bisphenanthroline units forming tetrahedral cavities was prepared. We show that these cavities not only allow the incorporation of C-u(2+) and E-u(3+) ions but also induce the reduction of these ions in C-u(+) and E-u(2+), respectively. The E-u(2+) containing material shows an extremely bright yellow luminescence and might be therefore a candidate for future applications.

  DOI：

  10.1021/ja075277e