tetrakis(triethyl phosphite)palladium(0) | 23066-14-0

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: tetrakis(triethyl phosphite)palladium(0)
• CAS: 23066-14-0
• 化学式: C₂₄H₆₀O₁₂P₄Pd
• 分子量: 771.048
• InChiKey: JBGQWFQJFQGYTN-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  tetrakis(triethyl phosphite)palladium(0) 、 足球烯 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  New organometallic complexes of buckminsterfullerene having π-bondend nickel, palladium, or platinum with triorganophosphite ligands, and their characterisation

  摘要：

  We have prepared a series of novel pi-complexes of fullerene C-60 of the types [C-60{M(P(OR)(3))(2)}(n)], (M = Ni, Pd, or Pt; R = Ph, Bu, or Et; n = 1 or 2). The compounds have been characterised by mass spectrometry, electronic spectroscopy and proton, carbon, and phosphorus NMR spectroscopy. The sensitivity of these compounds to air increases greatly in the series Pt < Pd << Ni. Unlike analogous phosphine derivatives, the phosphite species do not readily form complexes with more than two metal atoms attached to the fullerene cage. In contrast with many pi-bonded fullerene derivatives, most of the compounds show molecular ions in the FAB mass spectrum.

  DOI：

  10.1016/0022-328x(94)05249-b
• 作为产物：
  描述：

  palladium diacetate 、 亚磷酸三乙酯 以 苯 为溶剂， 以0%的产率得到tetrakis(triethyl phosphite)palladium(0)
  参考文献：
  名称：

  Belykh, L. B.; Shmidt, F. K.; Burlakova, O. V., Koordinatsionnaya Khimiya, 1990, vol. 16, p. 827 - 830

  摘要：

  DOI：
• 作为试剂：
  描述：

  亚磷酸二乙酯 、 (E,E)-1,4-diiodobuta-1,3-diene 在 tetrakis(triethyl phosphite)palladium(0) 、 三乙胺 作用下， 以 甲苯 为溶剂， 反应 1.5h， 以94%的产率得到E,E-buta-1,3-diene-1,4-diyldiphosphonate
  参考文献：
  名称：

  摘要：

  E,E-1,4-Diiodobuta-1,3-diene can enter into cross-coupling reactions with carbon- or other element-centered nucleophiles in the presence of Pd or Ni complexes as catalysts. Convenient procedures were developed for the stereoselective synthesis of E,E-1,4-dialkenylbuta-1,3-dienes, dienyl-1,4-bisphosphonates, E,E-1,4-bis(diphenylphosphino)buta-1,3-diene, E,E-1,4-diphenylbuta-1,3-diene, and E,E-1,4-bis(thiophenyl)buta-1,3-diene.

  DOI：

  10.1023/a:1015093100084