4,6-双（3,5-二（吡啶-4-基）苯基）-2-苯基嘧啶 | 1097652-83-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 中文名称: 4,6-双（3,5-二（吡啶-4-基）苯基）-2-苯基嘧啶
• 英文名称: B4PyPPM
• 英文别名: 2-Phenyl-4,6-bis[3,5-bis(4-pyridyl)phenyl]pyrimidine；4,6-bis(3,5-dipyridin-4-ylphenyl)-2-phenylpyrimidine
• CAS: 1097652-83-9
• 化学式: C₄₂H₂₈N₆
• 分子量: 616.725
• InChiKey: RXVALUXWPWFEMQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  48
• 可旋转键数：
  7
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  77.3
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  4-6-双(3,5-二氯苯基)-2-苯基嘧啶 、 4-吡啶硼酸频哪醇酯 在 potassium phosphate 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 、 三环己基膦 作用下， 以 1,4-二氧六环 、 水 、 乙腈 为溶剂， 反应 31.0h， 以68%的产率得到4,6-双（3,5-二（吡啶-4-基）苯基）-2-苯基嘧啶
  参考文献：
  名称：

  2-Phenylpyrimidine skeleton-based electron-transport materials for extremely efficient green organic light-emitting devices

  摘要：

  设计并合成了基于 2-苯基嘧啶骨架的多功能电子传输材料。利用这些材料和绿色磷光发光体--面-三(2-苯基吡啶)铱[Ir(ppy)3]，开发出了极其高效的绿色有机发光器件。这些器件在 100 cd m-2 和 1000 cd m-2 条件下的效率分别为 128 lm W-1 （105 cd A-1）和 96 lm W-1 （99 cd A-1）。

  DOI：

  10.1039/b812270a

文献信息

• ORGANIC ELECTROLUMINESCENCE DEVICE AND DISPLAY DEVICE INCLUDING THE SAME
  申请人：Samsung Display Co., Ltd.

  公开号：US20200220082A1

  公开（公告）日：2020-07-09

  Provided are an organic electroluminescence device and a display device including the same. The organic electroluminescence device includes a polycyclic compound represented by Formula 1 in a hole blocking layer and at least one of a first light emitting layer and an electron transport layer, wherein each of Y 1 to Y 5 and Y 11 to Y 15 is independently CH or N, at least four of Y 1 to Y 5 are CH, at least four of Y 11 to Y 15 are CH, and R 1 , R 2 , and R 3 are as disclosed in the description.

  提供了一种有机电致发光装置和包括该装置的显示装置。该有机电致发光装置包括式1所表示的多环化合物在阻挡空穴层和至少一个第一发光层和电子传输层中，其中Y1到Y5和Y11到Y15中的每一个都是独立的CH或N，Y1到Y5中至少有四个是CH，Y11到Y15中至少有四个是CH，R1、R2和R3如说明中所述。
• Organic electroluminescence device and display device including the same
  申请人：Samsung Display Co., Ltd.

  公开号：US11335857B2

  公开（公告）日：2022-05-17

  Provided are an organic electroluminescence device and a display device including the same. The organic electroluminescence device includes a polycyclic compound represented by Formula 1 in a hole blocking layer and at least one of a first light emitting layer and an electron transport layer, wherein each of Y1 to Y5 and Y11 to Y15 is independently CH or N, at least four of Y1 to Y5 are CH, at least four of Y11 to Y15 are CH, and R1, R2, and R3 are as disclosed in the description.

  本文提供了一种有机电致发光器件和一种包括该器件的显示器件。该有机电致发光器件包括在空穴阻挡层和第一发光层及电子传输层中的至少一层中的、由式 1 表示的多环化合物，其中 Y1 至 Y5 和 Y11 至 Y15 中的每一个都独立地为 CH 或 N，Y1 至 Y5 中的至少四个为 CH，Y11 至 Y15 中的至少四个为 CH，以及 R1、R2 和 R3 如描述中所公开。
• ORGANIC LIGHT EMITTING DIODES AND METHODS OF USE THEREOF
  申请人：NORTH CAROLINA STATE UNIVERSITY

  公开号：US20210036240A1

  公开（公告）日：2021-02-04

  Disclosed herein are organic light emitting diode (OLED) devices and methods of use thereof. In one embodiment, an organic light emitting diode (OLED) device includes an emitting layer including: a host and an emitter, wherein the host exhibits triplet-triplet annihilation up-conversion, wherein the emitter has a band gap and exhibits triplet-triplet annihilation up-conversion, wherein the host and the emitter are different, and wherein the emitter has a concentration of 5% or more in the emitting layer.
• BORON-CONTAINING COMPOUND AND ORGANIC LIGHT-EMITTING DIODE
  申请人：FLASK Corporation

  公开号：US20210257553A1

  公开（公告）日：2021-08-19

  Provided is a boron-containing compound suitable for the material of a blue light-emitting diode and an organic light-emitting diode using the same. The boron-containing compound has a structure represented by the formula (1): X is each independently —NR 1 —, —CR 2 R 3 —, —O— or —S—. In the —NR 1 — and —CR 2 R 3 —, R 1 to R 3 are each independently hydrogen, deuterium, an alkyl group having 1 to 6 carbon atoms or an aryl group having 5 to 30 core atoms, and R 2 and R 3 may connect with each other to form a ring. Cy 1 is an aryl group having 5 to 30 core atoms. All or part of hydrogen atoms in the formula (1) may be substituted by deuterium, a halogen, an alkyl group having 1 to 6 carbon atoms, an aryl group having 5 to 30 core atoms, a substituted or unsubstituted silyl group, a substituted or unsubstituted amino group, or cyano group.
• [EN] ORGANIC LIGHT EMITTING DIODES AND METHODS OF USE THEREOF<br/>[FR] DIODES ÉLECTROLUMINESCENTES ORGANIQUES ET LEURS PROCÉDÉS D'UTILISATION
  申请人：UNIV NORTH CAROLINA STATE

  公开号：WO2019195383A1

  公开（公告）日：2019-10-10

  Disclosed herein are organic light emitting diode (OLED) devices and methods of use thereof. In one embodiment, an organic light emitting diode (OLED) device includes an emitting layer including: a host and an emitter, wherein the host exhibits triplet-triplet annihilation up-conversion, wherein the emitter has a band gap and exhibits triplet-triplet annihilation up-conversion, wherein the host and the emitter are different, and wherein the emitter has a concentration of 5% or more in the emitting layer.