| 168479-77-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• CAS: 168479-77-4
• 化学式: C₁₂H₉N*Kr
• 分子量: 251.01
• InChiKey: MXRLIEAXKRFJNQ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  氪气 、 咔唑 生成
  参考文献：
  名称：

  van der Waals binding energies and intermolecular vibrations of carbazole⋅R (R=Ne, Ar, Kr, Xe)

  摘要：

  Mass-selective ground-state vibrational spectra of jet-cooled carbazole⋅R (R=Ne, Ar, Kr, and Xe) van der Waals complexes were obtained by populating ground-state intra- and intermolecular levels via stimulated emission pumping, followed by time delayed resonant two-photon ionization of the vibrationally hot complex. By tuning the dump laser frequency, S0 state vibrational modes were accessed from ≊200 cm−1 up to the dissociation energy D0. Upon dumping to ground-state levels above D0, efficient vibrational predissociation of the complexes occurred, allowing us to determine the S0 state van der Waals binding energies very accurately. The D0(S0) values are <214.5±0.5 cm−1 (R=Ne), 530.4±1.5 cm−1 (R=Ar), 687.9±4.0 cm−1 (R=Kr), and 890.8±1.6 cm−1 (R=Xe). In the S1 state, the corresponding binding energies are larger by 9% to 12%, being <222.9±1.0 cm−1, 576.3±1.6 cm−1, 756.4±4.5 cm−1, and 995.8±2.5 cm−1, respectively.

  DOI：

  10.1063/1.469589

文献信息

• Van der waals vibrations and binding energies of carbazole·Kr
  作者：Juerg Boesiger、Samuel Leutwyler

  DOI：10.1016/s0009-2614(86)80076-8

  日期：1986.5

  Intermolecular bonding between a large polar aromatic molecule (carbazole) and a rare gas atom (Kr) is characterized by several laser spectroscopic methods. Intermolecular vibrations and bond dissociation energies are measured for the So and S1 states. Detailed tests of model calculations incorporating dispersive and inductive interactions indicate that the latter contribution to the binding energy

  大极性芳族分子（咔唑）和稀有气体原子（Kr）之间的分子间键合是通过几种激光光谱方法来表征的。测量了S o和S 1状态的分子间振动和键解离能。结合色散和感应相互作用的模型计算的详细测试表明，后者对结合能的贡献约为15％。