| 876149-00-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• CAS: 876149-00-7
• 化学式: C₆₂H₆₀Ag₄F₆N₆O₆P₄S₆
• 分子量: 1846.95
• InChiKey: UCZBXQGVKDWZMK-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 以 四氢呋喃 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  Zwitterionic Metalates of Group 11 Elements and Their Use as Metalloligands for the Assembly of Multizwitterionic Clusters

  摘要：

  Reaction of RNHC(S)PPh2NPPh2C(S)NR (HRSNS; R = Me, Et) with M-I (M = Cu, Ag, Au) salts afforded zwitterionic complexes of the general formula [M(RSNS)l (M = Cu, Ag, Au). The ligand was found in the solid state in S,S-kappa(2) and S,N,S-kappa(3) coordination fashions. [Cu(RSNS)] and [Ag(RSNS)] can be used as metalloligand building blocks for the assembly of pentanuclear multizwitterionic Cu-5, Cu3Ag2 and Ag-5 core clusters of the general formula [M'(2){M(RSNS)}(3)]](2+) (M = Cu, M'= Cu, Ag; M = M'= Ag) upon reaction with suitable M' salts. The crystal structures of the most significant compounds are reported herein. Compound [Ag-2{Ag(RSNS)}(2)(OTf)(2)] was also isolated and structurally characterized, representing a model for the intermediate species of the aforementioned assembly.

  DOI：

  10.1021/ja0554110
• 作为产物：
  描述：

  、 silver trifluoromethanesulfonate 以 四氢呋喃 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  Zwitterionic Metalates of Group 11 Elements and Their Use as Metalloligands for the Assembly of Multizwitterionic Clusters

  摘要：

  Reaction of RNHC(S)PPh2NPPh2C(S)NR (HRSNS; R = Me, Et) with M-I (M = Cu, Ag, Au) salts afforded zwitterionic complexes of the general formula [M(RSNS)l (M = Cu, Ag, Au). The ligand was found in the solid state in S,S-kappa(2) and S,N,S-kappa(3) coordination fashions. [Cu(RSNS)] and [Ag(RSNS)] can be used as metalloligand building blocks for the assembly of pentanuclear multizwitterionic Cu-5, Cu3Ag2 and Ag-5 core clusters of the general formula [M'(2){M(RSNS)}(3)]](2+) (M = Cu, M'= Cu, Ag; M = M'= Ag) upon reaction with suitable M' salts. The crystal structures of the most significant compounds are reported herein. Compound [Ag-2{Ag(RSNS)}(2)(OTf)(2)] was also isolated and structurally characterized, representing a model for the intermediate species of the aforementioned assembly.

  DOI：

  10.1021/ja0554110