| 185107-63-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• CAS: 185107-63-5
• 化学式: C₁₆H₁₄FeN₃O₆
• 分子量: 400.151
• InChiKey: FDAUPYJIYNELBH-UHFFFAOYSA-K

反应信息

• 作为反应物：
  描述：

  氢气 、 以 水 为溶剂， 生成 diaqua(nitrilotriacetate)iron(III) 、 2,2'-bipyridinium
  参考文献：
  名称：

  Kinetics and equ libria of the ternary complex formation of nitrilotriacetatoferrate(III) with 2,2′-bipyridyl in aqueous solutions

  摘要：

  In the pH range 2.7-3.7, [Fe(nta)(H2O)(2)] (1) reacted with Hbipy(+) and bipy to form the ternary complex, [Fe(nta)(bipy)] (2), which was also formed in the reaction between [Fe(nta)(H2O)(OH)](-) and Hbipy(+). The equilibrium constant determined spectrophotometrically agreed well with the kinetically determined value. Rate constants and corresponding activation parameters have been evaluated for different pathways leading to compound 2 and its dissociation. Bond dissociation appears to be important in the transition state. The greater thermodynamic stability of [Fe(nta) (benzohydroxamate)](-) (3) than 2 is a consequence of a-much greater rate of dissociation of compound 2 than of compound 3; formation rate constants for compounds 2 and 3 are similar. Copyright (C) 1996 Elsevier Science Ltd

  DOI：

  10.1016/s0277-5387(96)00326-9
• 作为产物：
  描述：

  diaqua(nitrilotriacetate)iron(III) 、 2,2'-bipyridinium 以 水 为溶剂， 生成 氢气 、
  参考文献：
  名称：

  Kinetics and equ libria of the ternary complex formation of nitrilotriacetatoferrate(III) with 2,2′-bipyridyl in aqueous solutions

  摘要：

  In the pH range 2.7-3.7, [Fe(nta)(H2O)(2)] (1) reacted with Hbipy(+) and bipy to form the ternary complex, [Fe(nta)(bipy)] (2), which was also formed in the reaction between [Fe(nta)(H2O)(OH)](-) and Hbipy(+). The equilibrium constant determined spectrophotometrically agreed well with the kinetically determined value. Rate constants and corresponding activation parameters have been evaluated for different pathways leading to compound 2 and its dissociation. Bond dissociation appears to be important in the transition state. The greater thermodynamic stability of [Fe(nta) (benzohydroxamate)](-) (3) than 2 is a consequence of a-much greater rate of dissociation of compound 2 than of compound 3; formation rate constants for compounds 2 and 3 are similar. Copyright (C) 1996 Elsevier Science Ltd

  DOI：

  10.1016/s0277-5387(96)00326-9