6,25-Dithiaheptacyclo[15.11.0.02,14.03,11.04,8.020,28.023,27]octacosa-1(17),2(14),3(11),4,7,9,12,15,18,20(28),21,23,26-tridecaene | 1292832-23-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 6,25-Dithiaheptacyclo[15.11.0.02,14.03,11.04,8.020,28.023,27]octacosa-1(17),2(14),3(11),4,7,9,12,15,18,20(28),21,23,26-tridecaene
• CAS: 1292832-23-5
• 化学式: C₂₆H₁₄S₂
• 分子量: 390.529
• InChiKey: MBVRVDRCAXXXPQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.8
• 重原子数：
  28
• 可旋转键数：
  0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  56.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  3-[2-[6-(2-thiophen-3-ylethenyl)phenanthren-3-yl]ethenyl]thiophene 在 碘 、 methyloxirane 作用下， 以 甲苯 为溶剂， 以60%的产率得到6,25-Dithiaheptacyclo[15.11.0.02,14.03,11.04,8.020,28.023,27]octacosa-1(17),2(14),3(11),4,7,9,12,15,18,20(28),21,23,26-tridecaene
  参考文献：
  名称：

  Synthesis and Optoelectronic Properties of Some New Thiahelicenes

  摘要：

  [image omitted] New symmetrical helically chiral penta- and heptacyclic aromatic systems containing two thiophene rings have been prepared, in good yields, under mild conditions using a photochemical route. Optoelectronic properties of these helically aromatic thia-systems were determined and exhibit interesting behavior.

  DOI：

  10.1080/00397911003707220

文献信息

• Synthesis and Optoelectronic Properties of Some New Thiahelicenes
  作者：Souad Moussa、Faouzi Aloui、Béchir Ben Hassine

  DOI：10.1080/00397911003707220

  日期：2011.3.3

  [image omitted] New symmetrical helically chiral penta- and heptacyclic aromatic systems containing two thiophene rings have been prepared, in good yields, under mild conditions using a photochemical route. Optoelectronic properties of these helically aromatic thia-systems were determined and exhibit interesting behavior.