N-(2,6-diisopropylphenyl)-N'-(1,3-dicarboxypropyl)terrylene-3,4:11,12-carboxdiimide | 1093664-56-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N-(2,6-diisopropylphenyl)-N'-(1,3-dicarboxypropyl)terrylene-3,4:11,12-carboxdiimide
• CAS: 1093664-56-2
• 化学式: C₅₁H₃₆N₂O₈
• 分子量: 804.855
• InChiKey: OKJVPXFDARQXQP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.6
• 重原子数：
  61.0
• 可旋转键数：
  8.0
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  149.36
• 氢给体数：
  2.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  3-(6-(2-(2,6-diisopropylphenyl)-1,3-dioxo-2,3-dihydro-1H-benzo[10,5]anthra[2,1,9-def]isoquinolin-8-yl)-1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl)pentanedioic acid 在 potassium carbonate 、 C.I.酸性橙108 作用下， 反应 3.0h， 以28 mg的产率得到N-(2,6-diisopropylphenyl)-N'-(1,3-dicarboxypropyl)terrylene-3,4:11,12-carboxdiimide
  参考文献：
  名称：

  A Simple and Versatile Route to Stable Quantum Dot−Dye Hybrids in Nonaqueous and Aqueous Solutions

  摘要：

  Hybrid systems consisting of core/shell semiconductor quantum dots (QDs) and organic rylene dyes have been prepared and characterized. Complex formation is mediated by bidentate carboxylate moieties covalently linked to the dye molecules. The complexes were very stable with respect to time (at least months), dilution (sub nM), and precipitation. After preparation in organic solvent, complexes could be easily transferred into water. The strong quenching of QD emission by the dye molecules (transfer efficiencies up to 95%) was satisfactorily modeled by an FRET process. Single complexes immobilized in thin polymer films were imaged by confocal fluorescence microscopy.

  DOI：

  10.1021/ja8073962