cis-dimethylbis-(7-diethylamino-3-isocyanocoumarin) | 845674-89-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 香豆素及其衍生物
• 英文名称: cis-dimethylbis-(7-diethylamino-3-isocyanocoumarin)
• CAS: 845674-89-7
• 化学式: C₃₀H₃₄N₄O₄Pt
• 分子量: 709.704
• InChiKey: ZJMKZOFADZIJHQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  二氯甲烷 、 cis-dimethylbis-(7-diethylamino-3-isocyanocoumarin) 、 碘甲烷 以 丙酮 为溶剂， 以59%的产率得到[PtMe3I(7-diethylamino-3-isocyanocoumarin)2]*0.5CH2Cl2
  参考文献：
  名称：

  Dimethylplatinum (II) complexes with isocyanocoumarin ligands: the crystal structure of cis-dimethylbis-(7-diethylamino-3-isocyanocoumarin)platinum(II)

  摘要：

  Platinum complexes that contain isocyanocourmarin ligands have been prepared. [Pt2Me4(mu-SMe2)(2) and [PtPh2(SMe2)(2)] react with ligands L, (L = 7-diethylamino-3-isocyanocoumarin, Idc; 7-isocyano-4-methylcoumarin, Mic; 7-isocyano-4-trifluoromethylcoumarin, Tic; 3-chloro-4-methyl-7-isocyanocoumarin, Cmic), to give PtR2L2L2, monomers in high yield. The NMR and IR spectra of these complexes are consistent with cis stereochemistry. The UV-Vis absorption spectra of the complexes show bands assigned to ligand-centered transitions. Excitation into the absorption bands of the ldc complexes gives emission at room temperature in methylene chloride solution. The oxidative addition reaction of two of these complexes with methyl iodide has been studied. Platinum (IV) species with fac geometry have been isolated and characterized. Cis-dimethylbis-(7-diethylamino-3-isocyanocoumarin)platinum(II) was characterized by X-ray diffraction. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.09.007
• 作为产物：
  描述：

  7-diethylamino-3-isocyanocoumarin 、 bis[dimethyl(μ-dimethylsulfide)platinum(II)] 以 二氯甲烷 为溶剂， 以80%的产率得到cis-dimethylbis-(7-diethylamino-3-isocyanocoumarin)
  参考文献：
  名称：

  Dimethylplatinum (II) complexes with isocyanocoumarin ligands: the crystal structure of cis-dimethylbis-(7-diethylamino-3-isocyanocoumarin)platinum(II)

  摘要：

  Platinum complexes that contain isocyanocourmarin ligands have been prepared. [Pt2Me4(mu-SMe2)(2) and [PtPh2(SMe2)(2)] react with ligands L, (L = 7-diethylamino-3-isocyanocoumarin, Idc; 7-isocyano-4-methylcoumarin, Mic; 7-isocyano-4-trifluoromethylcoumarin, Tic; 3-chloro-4-methyl-7-isocyanocoumarin, Cmic), to give PtR2L2L2, monomers in high yield. The NMR and IR spectra of these complexes are consistent with cis stereochemistry. The UV-Vis absorption spectra of the complexes show bands assigned to ligand-centered transitions. Excitation into the absorption bands of the ldc complexes gives emission at room temperature in methylene chloride solution. The oxidative addition reaction of two of these complexes with methyl iodide has been studied. Platinum (IV) species with fac geometry have been isolated and characterized. Cis-dimethylbis-(7-diethylamino-3-isocyanocoumarin)platinum(II) was characterized by X-ray diffraction. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.09.007