aluminium octa(pentoxy)phthalocyanine radical | 874445-71-3

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: aluminium octa(pentoxy)phthalocyanine radical
• 英文别名: AlPc(*)
• CAS: 874445-71-3
• 化学式: C₇₂H₉₆AlN₈O₈
• 分子量: 1228.58
• InChiKey: LOESZMFLEQIZBL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  aluminium octa(pentoxy)phthalocyanine radical 、 碘 以 氘代苯 为溶剂， 生成 aluminium octa(pentoxy)phthalocyanine iodide
  参考文献：
  名称：

  Aluminum and lithium octa(pentoxy)phthalocyanine radicals

  摘要：

  A lithium phthalocyanine radical and the analogous aluminum phthalocyanine radical were synthesized as part of an investigation of isostructural dopants. An improved synthesis of the free base of octa(pentoxy)phthalocyanine (H2Pc*) involves the reduction of 1,2-dicyano-4,5-dipentoxybenzene with hydroquinone. Deprotonation with lithium bis(trimethylsilyl)amide leads to the dilithium derivative Li2Pc* and subsequent oxidation with ferrocenium yields the radical LiPc*. Treatment of H2Pc* with Et2AlCl gives ClAlPc* and reduction with sodium amalgam yields AlPc*, the first reported aluminum phthalocyanine radical. In the solid state LiPc* and AlPc* are electrical conductors with pressed-pellet conductivities of 8 x 10(-11) Omega(-1) cm(-1) and 5 x 10(-7) Omega(-1) cm(-1), respectively. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.06.021
• 作为产物：
  描述：

  aluminium octa(pentoxy)phthalocyanine chloride 在 sodium amalgam 作用下， 以 四氢呋喃 为溶剂， 以80%的产率得到aluminium octa(pentoxy)phthalocyanine radical
  参考文献：
  名称：

  Aluminum and lithium octa(pentoxy)phthalocyanine radicals

  摘要：

  A lithium phthalocyanine radical and the analogous aluminum phthalocyanine radical were synthesized as part of an investigation of isostructural dopants. An improved synthesis of the free base of octa(pentoxy)phthalocyanine (H2Pc*) involves the reduction of 1,2-dicyano-4,5-dipentoxybenzene with hydroquinone. Deprotonation with lithium bis(trimethylsilyl)amide leads to the dilithium derivative Li2Pc* and subsequent oxidation with ferrocenium yields the radical LiPc*. Treatment of H2Pc* with Et2AlCl gives ClAlPc* and reduction with sodium amalgam yields AlPc*, the first reported aluminum phthalocyanine radical. In the solid state LiPc* and AlPc* are electrical conductors with pressed-pellet conductivities of 8 x 10(-11) Omega(-1) cm(-1) and 5 x 10(-7) Omega(-1) cm(-1), respectively. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.06.021