| 1609655-85-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• CAS: 1609655-85-7
• 化学式: C₁₆H₂₆N₂O₃
• 分子量: 294.394
• InChiKey: XXXYNGYJFDSJJV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.83
• 重原子数：
  21.0
• 可旋转键数：
  4.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  54.7
• 氢给体数：
  1.0
• 氢受体数：
  5.0

反应信息

• 作为产物：
  描述：

  4-(3-(pyrrol-1-yl)propionyloxy)-2,2,6,6-tetramethylpiperidin-1-yloxy 在 D-异抗坏血酸 作用下， 生成
  参考文献：
  名称：

  Electrochemical Polymerization of Pyrrole Containing TEMPO Side Chain on Pt Electrode and Its Electrochemical Activity

  摘要：

  Poly(4-(3-(pyrrol-1-yl)propionyloxy)-2,2,6,6-tetramethylpiperidin-1-yloxy) (PPy-TEMPO) electrode is prepared by electrochemical polymerization on Pt electrode in NaClO4-CH3CN solution. The electrocatalytic activity of PPy-TEMPO for benzyl alcohol in NaClO4-CH3CN solution is investigated by cyclic voltammetry and in situ FTIR. Results show that PPy-TEMPO electrode exhibits high electrocatalytic activity for benzyl alcohol oxidation in the presence of 2,6-lutidine as the base, as compared with the bare Pt electrode under the similar conditions. On the basis of in situ FTIR data, it shows that TEMPO is oxidized to its cation at the potential about 0.4V, and benzyl alcohol is oxidized to benzaldehyde instead of benzoic acid. Further studies of preparative electrolysis experiments by constant current electrolysis are carried out to confirm the high conversion to benzaldehyde, and the results are in good agreement with those from in situ FTIR investigations. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.electacta.2014.03.028