1-bromo-1-deuterio-propadiene | 33586-94-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: 1-bromo-1-deuterio-propadiene
• CAS: 33586-94-6
• 化学式: C₃H₃Br
• 分子量: 119.953
• InChiKey: UUIORUQWCRSGJS-WFVSFCRTSA-N

反应信息

• 作为产物：
  描述：

  3-bromoprop-1-yne-1,3,3-d3 以 氘代二甲亚砜 为溶剂， 反应 2.0h， 生成 1-bromo-1-deuterio-propadiene
  参考文献：
  名称：

  Photorearrangement of Propargyl Bromide as a Probe to Study Propargylic and Allenic Radicals by Infrared Matrix Isolation Technique

  摘要：

  AbstractThe photolysis of propargyl bromide in Ar matrix to form allenyl bromide proceeded with a radical mechanism. The deuterium label study and radical scavenger were used to investigate the mechanism. Neither propargyl nor allenyl radical was trapped in Ar matrix at 8 K. The rates of propargyl and allenyl radicals coupled with bromo radical are significantly fast. The stability of propargyl and allenyl radicals is discussed.

  DOI：

  10.1002/jccs.199800049