| 142903-70-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• CAS: 142903-70-6
• 化学式: C₁₄H₂₃CuNO₅
• 分子量: 348.886
• InChiKey: JAHGNSVIDKDXIT-LTCKWSDVSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 copper(II) acetate monohydrate 以 水 为溶剂， 以35%的产率得到
  参考文献：
  名称：

  Preparation and study of amino acid (DL-leucine, L-isoleucine, L-histidine) Schiff bases with ethyl-α-ketocyclopentylcarboxylate and the corresponding copper(II) complexes

  摘要：

  Amino acid Schiff bases with ester function K(Rleu) . 2H2O (1), K(Rile) . 2H2O (2), K(Rhis) . H2O (3) (Rleu, Rile and Rhis represent the Schiff base Of DL-leucine, L-isoleucine and L-histidine, and ethyl-alpha-ketocyclopentylcarboxylate) were synthesized. Compounds 1, 2 and 3 were characterized by H-1 NMR spectroscopy. The copper(II) complexes, Cu(Rleu') . H2O (4), Cu[Rile'] . H2O (5) and Cu(Rhis') . 2H2O (6), were obtained with the N-deprotonated Schiff bases (Rleu', Rile' and Rhis'). The COO stretching bands in their IR spectra suggest that the carboxylate acts as a monodentate group when binding with copper. The temperature dependence of the susceptibility for 6 may be fit to the Curie-Weiss expression chi = 0.32/(T-26.2) emu mol-1 K-1. The dehydration process of 6 leads to the anhydrous compound, enthalpy (53 +/- 2kJ mol-1) and activation energy (82 +/- 5 kJ mol-1).

  DOI：

  10.1016/s0020-1693(00)83848-7