[Cu(2-[(2-hydroxyphenyl)methylene]hydrazinecarbothioamine)(PPh3)2Br] | 194875-55-3

• 英文名称: [Cu(2-[(2-hydroxyphenyl)methylene]hydrazinecarbothioamine)(PPh3)2Br]
• CAS: 194875-55-3
• 化学式: C₄₄H₃₉BrCuN₃OP₂S
• 分子量: 863.277
• InChiKey: HXBPJXBXSPAMNJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  水杨醛缩氨基硫脲 、 三苯基膦 、 copper(I) bromide 以 neat (no solvent, solid phase) 为溶剂， 以86.6%的产率得到[Cu(2-[(2-hydroxyphenyl)methylene]hydrazinecarbothioamine)(PPh3)2Br]
  参考文献：
  名称：

  Solid state syntheses and crystal structures of [Cu(HOC6H4CHNNHCSNH2) (PPh3)2X] (X = I, Br)

  摘要：

  The complexes [Cu(L)(PPh3)(2)X] [L-1 = 2-[(4-hydroxyphenyl methylene)]hydrazinecarbothioamine, X = I(I) and L-2 = 2-[(2-hydroxyphenyl methylene)]hydrazinecarbothioamine, X = Br(II) were obtained by the solid state reaction of L, CuX, PPh3 and characterized by elemental analysis, IR and UV-Vis spectroscopy. The crystal structures have been determined by single crystal X-ray diffraction. The copper atom is coordinated tetrahedrally by two phosphine atoms from PPh3, one halogen atom and one sulfur atom from L acting as a monodentate ligand. In the compound (I), two molecules and two solvents MeCN molecules are in the asymmetric unit. The Cu-S bond lengths are 2.402(3) Angstrom for molecule A and 2.376(3) Angstrom for molecule B; respectively. In the compound (II): one solvate MeCN molecule is in the asymmetric unit; the Cu-S bond length is 2.379(3) Angstrom. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00129-0