[Pd(OAc)(SCH2CH2CH2NMe2)]2*H2O | 884325-17-1

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: [Pd(OAc)(SCH2CH2CH2NMe2)]2*H2O
• CAS: 884325-17-1
• 化学式: C₁₄H₃₀N₂O₄Pd₂S₂*H₂O
• 分子量: 585.39
• InChiKey: VBUMVJIVIVPVKE-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis[3-(N,N-dimethylamino)propyl]disulfide 以 甲醇 、 丙酮 、 甲苯 为溶剂， 生成 [Pd(OAc)(SCH2CH2CH2NMe2)]2*H2O
  参考文献：
  名称：

  3-Dimethylaminopropyl chalcogenolate complexes of palladium(II): Syntheses and characterization, including the crystal structures of [Pd(OAc)(ECH2CH2CH2NMe2)]2·H2O (E=S, Se) and [PdCl(TeCH2CH2CH2NMe2)]2

  摘要：

  The reactions of the sodium salts of 3-dimethylamino-l-propylchalcogenolates, prepared by sodium borohydride reduction of (Me2NCH2CH2CH2E)(2) in methanol, with Na2PdCl4 yielded homoleptic [Pd(ECH2CH2CH2NMe2)(2)](6) (1) (E=S (1a); Se (1b); Te (1c)). When treated with [Pd(OAc)(2)](3) or Na2PdCl4, compounds 1 readily gave binuclear redistribution products [PdX(ECH2CH2CH2NMe2))(2) where X = OAc (2) (E = S (2a); Se (2b); or Cl (3)) (E = S (3a); Se (3b); Te (3c)), respectively. The terminal acetate/chloride ligands in 2b/3b can be substituted by other ionic ligands like PhSe-. The complexes were characterized by elemental analysis, UV-Vis, IR and NMR spectroscopy. The structures of 2a, 2b and 3c were established by X-ray crystallography. Each molecule has a dimeric structure in which there are two chalcogenolate bridges from the chelating 3-dimethylamino-l-propylchalcogenolate ligands. On pyrolysis, compound 2b affords Pd17Se15. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.09.019