5,11,17,23-tetra-tert-butyl-25,26,27,28-tetrakis[(2-pyridinylidene)hydrazinocarbonylmethyloxy]-2,8,14,20-tetrathiacalix[4]arene | 960319-18-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetrakis[(2-pyridinylidene)hydrazinocarbonylmethyloxy]-2,8,14,20-tetrathiacalix[4]arene
• CAS: 960319-18-0
• 化学式: C₇₂H₇₆N₁₂O₈S₄
• 分子量: 1365.74
• InChiKey: ZLMLYDARIILHAR-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  吡啶-2-甲醛 、 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetrakis-[(hydrazidocarbonyl)methoxy]-2,8,14,20-tetrathiacalix[4]arene 以 乙醇 为溶剂， 反应 6.0h， 以80%的产率得到5,11,17,23-tetra-tert-butyl-25,26,27,28-tetrakis[(2-pyridinylidene)hydrazinocarbonylmethyloxy]-2,8,14,20-tetrathiacalix[4]arene
  参考文献：
  名称：

  Synthesis of tetrathiacalix[4]arene functionalised by acetylhydrazone fragments

  摘要：

  The reactions of tetrathiacalix[4]arene: functionalised by acetylhydrazide groups with an excess of 4-nitrobenzaldehyde or tetrathiacalix[4]arene functionalised by chlorocarbonylmethoxy groups with an excess of 4-nitrobezaldehyde hydrazone lead to the preferable formation of tetrathiacalix[4]arene with an additional NW-diacetylhydrazine bridge, but in the case of pyridine-2-carboxaldehyde, only to the formation of tetrathiacalix[4]arene functionalised by four acetylhydrazone fragments.

  DOI：

  10.1070/mc2006v016n06abeh002404