hexakis[(1,4-dicyanobutane-1,4-diyl)-nickel(II)] complex | 165462-08-8

• 分子结构分类: 有机化合物
• 英文名称: hexakis[(1,4-dicyanobutane-1,4-diyl)-nickel(II)] complex
• CAS: 165462-08-8
• 化学式: C₃₆H₃₆N₁₂Ni₆
• 分子量: 988.902
• InChiKey: PLDJDNFIGUHXPV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(1,5-cyclooctadiene)nickel (0) 、 2,2'-二吡啶胺 、 丙烯腈 以 四氢呋喃 为溶剂， 以20%的产率得到hexakis[(1,4-dicyanobutane-1,4-diyl)-nickel(II)] complex
  参考文献：
  名称：

  Formation of a metallocycle by dimerization of acrylonitrile. Crystal structure of the hexakis{(1,4-dicyanobutane-1,4-diyl)-nickel(II)} complex

  摘要：

  A novel hexanickel(II) complex [Ni-6(NCCHCH2CH2CHCN)(6)] (2) with 1,4-dicyanobutane-1,4-diyl (L) which was produced by the metal-induced dimerization of acrylonitrile (AN) has been isolated and the structure has been determined crystallographically. Complex 2 is triclinic, space group P (1) over bar, a=9.998(2), b=10.363(2), c=9.960(3) Angstrom, alpha=110.35(2), beta=103.46(2), gamma=88.97(2)degrees U=938.7(4) Angstrom(3), Z=1, R=0.029 and R(w)=0.034. Each nickel atom is coordinated by two carbon atoms of L and two nitrogen atoms of the cyano group of two other L, providing a square-planar geometry. The six nickel atoms are bridged by the cyano group and carbon atom to form the slightly distorted octahedral Ni-6 core.

  DOI：

  10.1016/0020-1693(94)04305-f