2-(2'-hydroxynaphth-1'-yl)-3,4-dimethyl-5-phenyl-η5-phospholyl(pentamethylcyclopentadienyl)ruthenium(II) | 942608-40-4

• 英文名称: 2-(2'-hydroxynaphth-1'-yl)-3,4-dimethyl-5-phenyl-η5-phospholyl(pentamethylcyclopentadienyl)ruthenium(II)
• CAS: 942608-40-4
• 化学式: C₃₂H₃₃OPRu
• 分子量: 565.657
• InChiKey: XYHAXGCALJNESD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  2-(2'-hydroxynaphth-1'-yl)-3,4-dimethyl-5-phenyl-η5-phospholyl(pentamethylcyclopentadienyl)ruthenium(II) 、 4-硝基苯酚三氟甲基磺酸酯 在 potassium carbonate 、 18-crown-6 作用下， 以 四氢呋喃 为溶剂， 以73%的产率得到2-(2'-trifluoromethanesulfonyloxynaphth-1'-yl)-3,4-dimethyl-5-phenyl-η5-phospholyl(pentamethylcyclopentadienyl)ruthenium(II)
  参考文献：
  名称：

  Planar-to-Axial Chirality Relay in Phospharuthenocenes. A Rotationally Hindered 2-(2‘-Diphenylphosphinonaphth-1‘-yl)phospharuthenocene

  摘要：

  Competing steric pressures within the coordination sphere of 2-(2'-X-naphth-1'-yl)-3,4-dimethyl-5-phenyl-eta(5)-phospholyl(pentamethylcyclopentadienyl)ruthenium(II) complexes (X = OMe (1), OH (3), OTf (4), PPh2(O) (5), PPh2 (6)) give rise to a well-defined and predictable axial chirality about the phospharuthenocene-naphthyl bond. Crystal structure analysis of the platinum complex cis-[Pt(6)Cl-2] (7) shows a very different geometry from that found in cis-[Pt(1)(PEt3)Cl-2] (2) because of the leverage exerted on the Pt coordination sphere by the (2'-PPh2-naphth-1'-yl) functionality.

  DOI：

  10.1021/om0610905
• 作为产物：
  描述：

  η5-pentamethylcyclopentadienyl(η5-2-(2'-methoxynaphth-1'-yl)-3,4-dimethyl-5-phenylphospholyl)ruthenium(II) 、 水 在 lithium diphenylphosphide*2(tetrahydrofuran) 作用下， 以 水 为溶剂， 以87%的产率得到2-(2'-hydroxynaphth-1'-yl)-3,4-dimethyl-5-phenyl-η5-phospholyl(pentamethylcyclopentadienyl)ruthenium(II)
  参考文献：
  名称：

  Planar-to-Axial Chirality Relay in Phospharuthenocenes. A Rotationally Hindered 2-(2‘-Diphenylphosphinonaphth-1‘-yl)phospharuthenocene

  摘要：

  Competing steric pressures within the coordination sphere of 2-(2'-X-naphth-1'-yl)-3,4-dimethyl-5-phenyl-eta(5)-phospholyl(pentamethylcyclopentadienyl)ruthenium(II) complexes (X = OMe (1), OH (3), OTf (4), PPh2(O) (5), PPh2 (6)) give rise to a well-defined and predictable axial chirality about the phospharuthenocene-naphthyl bond. Crystal structure analysis of the platinum complex cis-[Pt(6)Cl-2] (7) shows a very different geometry from that found in cis-[Pt(1)(PEt3)Cl-2] (2) because of the leverage exerted on the Pt coordination sphere by the (2'-PPh2-naphth-1'-yl) functionality.

  DOI：

  10.1021/om0610905