4-(hexyloxy)-N-(4-(hexyloxy)phenyl)-N-phenylaniline | 1146433-75-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-(hexyloxy)-N-(4-(hexyloxy)phenyl)-N-phenylaniline
• 英文别名: N,N-(di-4-n-hexyloxyphenyl)aniline；N,N-bis(4-hexyloxyphenyl)aniline；4,4-dihexyloxytriphenylamine；N,N-bis-(4-hexyloxylphenyl)aniline；4-hexoxy-N-(4-hexoxyphenyl)-N-phenylaniline
• CAS: 1146433-75-1
• 化学式: C₃₀H₃₉NO₂
• 分子量: 445.645
• InChiKey: ZMDVJBLKCRYDRR-UHFFFAOYSA-N

物化性质

• 沸点：
  566.9±35.0 °C(Predicted)
• 密度：
  1.027±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9.8
• 重原子数：
  33
• 可旋转键数：
  15
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  21.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-(hexyloxy)-N-(4-(hexyloxy)phenyl)-N-phenylaniline 在 (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 、 碘 、 potassium acetate 、 高碘酸 作用下， 以 乙醇 、 二甲基亚砜 为溶剂， 反应 49.0h， 生成 N,N-双(4-(己氧基)苯基)胺-4-频哪醇酯
  参考文献：
  名称：

  4,9-Dihydro-4,4,9,9-tetrahexyl-s-indaceno[1,2-b:5,6-b′]dithiophene as a π-Spacer of Donor−π–Acceptor Dye and Its Photovoltaic Performance with Liquid and Solid-State Dye-Sensitized Solar Cells

  摘要：

  A new D-pi-A organic dye, LC-5, containing 4,9-dihydro-4,4,9,9-tetrahexyl-s-indaceno[1,2-b:5,6-b']-dithiophene as a novel pi-conjugated spacer has been synthesized and tested as a sensitizer in dye-sensitized solar cells (DSC). Volatile and ionic liquid electrolytes have been used in conjunction with the synthesized dye, and the electrolyte influence on the photovoltaic performance of DSCs was investigated. A detailed investigation, including transient photocurrent/photovoltage decay measurements and electrochemical impedance spectroscopy data, provide important conclusions about the influence of electrolytes on the photovoltaic parameters.

  DOI：

  10.1021/ol402749s
• 作为产物：
  描述：

  4-碘苯酚 在 copper(l) iodide 、 1,10-菲罗啉 、 potassium carbonate 作用下， 以 丙酮 、 甲苯 为溶剂， 反应 25.0h， 生成 4-(hexyloxy)-N-(4-(hexyloxy)phenyl)-N-phenylaniline
  参考文献：
  名称：

  The effect of different alkyl chains on the photovoltaic performance of D–π–A porphyrin-sensitized solar cells

  摘要：

  与基于具有短烷基链的WH-C1和YD20的DSSCs相比，由带有己氧基团的WH-C2敏化的器件显示出明显增强的V_oc、J_sc和功率转换效率（η）。

  DOI：

  10.1039/c4nj02263g

文献信息

• Pyrazino-[2,3-f][1,10]phenanthroline as a new anchoring group of organic dyes for dye-sensitized solar cells
  作者：Li-Peng Zhang、Ke-Jian Jiang、Qiang Chen、Gang Li、Lian-Ming Yang

  DOI：10.1039/c5ra05349h

  日期：——

  Two novel donor–acceptor organic dyes (PPL-1 and PPL-2) with pyrazino-[2,3-f][1,10]phenanthroline as an electron-withdrawing anchoring group displayed a promising power conversion efficiency of 4.04% under standard AM 1.5 conditions.

  两种新型供体-受体有机染料（PPL-1和PPL-2），具有吡嗪[2,3-f][1,10]菲啰啉作为电子吸引锚定基团，在标准AM 1.5条件下展示了有希望的光电转换效率为4.04%。
• Optical and electrochemical effects of triarylamine inclusion to alkoxy BODIPY-based derivatives
  作者：Juan S. Rocha-Ortiz、Alberto Insuasty、Duvalier Madrid-Usuga、Ana G. Mora-León、Alejandro Ortiz

  DOI：10.1039/d1nj02610k

  日期：——

  broader absorption in the visible region as a result of the inclusion of donor groups and extended conjugation of the BODIPY core. Fluorescence quenching was also observed, which was attributed to the photoinduced electron transfer, evidenced from solvatochromic measurements, quantum yields and theoretical calculations. The oxidation potentials of new compounds were found to be lower when compared with

  已经设计并合成了三种新的三苯胺-BODIPY二元组BDPT1-3。研究了它们的光电特性，揭示了供体和受体部分之间的强电子相互作用，以及对包含烷氧基的高灵敏度。将二元组的性质与参考化合物A和BDP1的性质进行比较，由于包含供体基团和 BODIPY 核心的扩展共轭，其在可见光区表现出更广泛的吸收。还观察到荧光猝灭，这归因于光致电子转移，这从溶剂化变色测量、量子产率和理论计算中得到证实。与其他附有供体基团的 BODIPY 类似物相比，发现新化合物的氧化电位较低。氧化还原、计算、吸光度和发射数据表明化合物BDPT1-3在有机光伏或发光（光电）器件中的应用表现出有希望的特性。
• Molecular design of triarylamine dyes incorporating phenylene spacer and the influence of alkoxy substituent on the performance of dye-sensitized solar cells
  作者：Hongyu Han、Mao Liang、Kai Tang、Xiaobing Cheng、Xueping Zong、Zhe Sun、Song Xue

  DOI：10.1016/j.jphotochem.2011.09.019

  日期：2011.12

  Molecular design and understanding the structure–property relationship of π-conjugated spacer play pivotal roles in realization of considerable enhancement performance of dye-sensitized solar cells (DSSCs). Three triphenylmaine dyes, namely MX11-13, have been designed and synthesized, which incorporate 2,2,6,6-tetramethylbenzo[1,2-d;4,5-d′]bis[1,3]dioxole (TMBD), phenyl and 1,4-dipropoxybenzene (DPB)

  分子设计和理解π共轭间隔基的结构-性质关系在实现染料敏化太阳能电池（DSSC）的显着增强性能方面起着关键作用。已经设计和合成了三种三苯基ma染料，即MX11-13，它们掺入了2,2,6,6-四甲基苯并[1,2- d ; 4,5- d ']双[1,3]二恶唑（TMBD）分别为苯基和1,4-二丙氧基苯（DPB）作为π共轭间隔基。研究了烷氧基取代基对染料敏化太阳能电池的光物理，电化学特性和性能的影响。对于典型设备，基于MX13的电池可提供整体功率转换效率（η）7.02％，与短路光电流密度（Ĵ SC），开路电压（V OC）和填充因子（FF的15.5毫安厘米）-2，697毫伏和0.65，分别。
• Isodiketopyrrolopyrrole dye and use thereof
  申请人：SOUTH CHINA UNIVERSITY OF TECHNOLOGY

  公开号：US11056287B2

  公开（公告）日：2021-07-06

  The present invention discloses an isodiketopyrrolopyrrole dye and use thereof. A series of pure organic dye based on isodiketopyrrolopyrrole are synthesized in the present invention, using 4,4′-dihexyloxytriphenylamine as an electron donor, isodiketopyrrolopyrrole as a π-bridge, and cyanoacetic acid as an electron acceptor and an anchoring group, and with a alkyl chain introduced on an isodiketopyrrolopyrrole group. The types of dyes have a relatively good light-harvesting performance as well as a relatively large steric hindrance, and they are not easy to gather while being absorbed on a semiconducting film. The pure organic dye with isodiketopyrrolopyrrole as an electronic π-bridge, which is used in a dye-sensitized solar cell, has a good ability of inhibiting the recombination of electrons, and the dye-sensitized solar cells have a high photoelectric conversion efficiency.

  本发明公开了一种异二酮吡咯啉染料及其用途。本发明以4,4′-二己氧基三苯胺为电子供体，异二酮吡咯为π桥，氰基乙酸为电子受体和锚定基，并在异二酮吡咯基团上引入烷基链，合成了一系列基于异二酮吡咯的纯有机染料。这类染料具有相对较好的光收集性能和相对较大的立体阻碍，在半导体薄膜上吸收时不易聚集。以异二酮基吡咯啉为电子π桥的纯有机染料用于染料敏化太阳能电池，具有良好的抑制电子重组的能力，染料敏化太阳能电池具有较高的光电转换效率。
• Photoelectric conversion element, dye-sensitized solar cell, metal complex dye, dye composition, and oxide semiconductor electrode
  申请人：FUJIFILM Corporation

  公开号：US11094474B2

  公开（公告）日：2021-08-17

  A photoelectric conversion element includes a conductive support, a photoconductor layer including an electrolyte, a charge transfer layer including an electrolyte, and a counter electrode, in which the photoconductor layer has semiconductor fine particles carrying a metal complex dye represented by a specific formula.

  一种光电转换元件包括导电支架、包括电解质的光电导体层、包括电解质的电荷转移层和对电极，其中光电导体层具有携带以特定公式表示的金属络合染料的半导体微粒。