1,8,15,22-tetraaminonickel phthalocyanine | 128313-72-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: 1,8,15,22-tetraaminonickel phthalocyanine
• 英文别名: 4,4',4'',4'''-tetra-aminophthalocyanine, Ni complex；nickel(II) 1,8,15,22-tetraaminophthalocyanine；1,8,15,22-tetraaminophthalocyanatonickel(II)；nickel(II) 3,3',3'',3'''-tetraamino phthalocyanine；4α-Ni(II)TAPc；Nickel(II) 1,8,15,22-tetra(amino)phthalocyanine；2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13(18),14,16,19(39),20,22(27),23,25,28,30(37),31(36),32,34-nonadecaene-5,14,23,32-tetramine;nickel(2+)
• CAS: 128313-72-4
• 化学式: C₃₂H₂₀N₁₂Ni
• 分子量: 631.281
• InChiKey: FQXZQKSOVQZODF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.45
• 重原子数：
  45
• 可旋转键数：
  0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  180
• 氢给体数：
  4
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  1,8,15,22-tetraaminonickel phthalocyanine 在 盐酸 、 sodium nitrite 、 copper(l) chloride 作用下， 生成 nickel(II) 1,8,15,22-tetrachlorophthalocyanine
  参考文献：
  名称：

  Synthesis, spectral and magnetic susceptibility studies on tetrachloro metal(II)phthalocyanines

  摘要：

  The present paper describes a simple method for the synthesis of symmetrically substituted 1,8,15,22-tetrachloro phthalocyanines of copper, cobalt, nickel and zinc. The title complexes are synthesized from the corresponding tetraamino metal phthalocyanines by modified Sandmeyers method and in turn the tetraamino metal phthalocyanines are prepared from 3-nitrophthalic acid. The bluish-green coloured tetrachloro metal phthalocyanine complexes are characterized by elemental, electronic, IR, magnetic susceptibility and X-ray powder diffraction studies to check the purity and the structural integrity. The magnetic susceptibility studies revealed that, the experimental values are higher than that of the spin only value magnetic moment, and the presence of intermolecular co-operative effects. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2005.05.012
• 作为产物：
  描述：

  1,8,15,22-tetranitronickel phthalocyanine 在 sodiumsulfide nonahydrate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 1,8,15,22-tetraaminonickel phthalocyanine
  参考文献：
  名称：

  废物燃料：通过配体异构化直接从农业沼渣中电合成氨

  摘要：

  我们证明，只需稍微改变配体异构化（α 和 β 异构体）即可选择性地激活用于氨生产的催化金属中心，使其即使对于农业废水也实用且有效。 β异构体的法拉第效率几乎为 90%，可产生约 0.64 mg h -1 cm -2的氨。 β-异构化产生的界面质子电荷组装可以吸引反应中的硝酸盐并排斥竞争性水合氢离子，从而实现节能的氨回收。这种异构化方法能够以最低的能耗将农业废水转化为氨燃料，理论收率高达 84%，并在连续电解 100 小时以上的情况下保持稳定性。

  DOI：

  10.1039/d4gc00740a

文献信息

• Synthesis, structural investigations and biological studies on symmetrically substituted 3,3′,3",3"′-tetra-methoxyphenylimino phthalocyanine complexes
  作者：M. H. Moinuddin khan、Fasiulla、J. Keshavayya、K. R. Venugopala Reddy

  DOI：10.1134/s0036023608010117

  日期：2008.1

  The present paper describes the synthesis and characterization of novel metal (II) 3,3',3aEuro(3),3aEuro '-tetramethoxyphenylimino substituted phthalocyanines (M-MeOPhImPcs) of copper (II), cobalt (II), nickel (II) and zinc (II) by condensing the 3,3',3aEuro(3),3aEuro(3)aEuro(2)-tetra amino phthalocyanines with anisaldehyde. The dark bluish green colored tetraimino substituted phthalocyanine derivatives were characterized by various physico-chemical techniques like elemental analysis, magnetic susceptibility, electronic, IR, powder X-ray diffraction and thermo gravimetric analysis (TGA) to check the structural integrity and purity. The variations of magnetic moment as a function of field strength indicated the presence of inter molecular co-operative interactions. The complexes were also evaluated for their antifungal and antibacterial activities.
• Amino group positions dependent morphology and coverage of electropolymerized metallophthalocyanine (M=Ni and Co) films on electrode surfaces
  作者：A. Sivanesan、S. Abraham John

  DOI：10.1016/j.electacta.2008.04.052

  日期：2008.9

  Electropolymerized films of teraaminometallophthalocyanines (MTAPc; M = Ni and Co) with amino groups at alpha-(4 alpha-MTAPc) and beta-(4 beta-MTAPc) positions were prepared on glassy carbon (GC) and indium tin oxide (ITO) electrodes. It was found that the electropolymerization growth rate of 4 alpha-MTAPc was less than that of 4 beta-MTAPc prepared under identical conditions. Further, the surface coverage of the polymerized 4 beta-MTAPc film was greater than that of 4 alpha-MTAPc polymerized film. Atomic force microscopy (AFM), X-ray diffraction (XRD) and UV-visible spectroscopic studies were carried out for the polymerized films of 4 alpha-Ni(II)TAPc(p-4 alpha-Ni(II)TAPc) and 4 beta-Ni(II)TAPc(p-4 beta-Ni(II)TAPc) alone because both Ni(II) and Co(II) polymerized films show similar trend in electropolymerization and surface coverage values. AFM images show that p-4 alpha-Ni(II)TAPc film contains islands and the thickness of this film was nearly three times less than that of p-4 beta-Ni(II)TAPc. XRD patterns for the two polymerized films reveal that p-4 beta-Ni(II)TAPc film was relatively more crystalline than p-4 alpha-Ni(II)TAPc film. Further, the compactness of these films was scrutinized from their barrier properties toward [Fe(CN)(6)](3-/4-) redox couple. The differences in the polymerization growth rate of 4a-MTAPc and 4 beta-MTAPc, and the thicknesses of the resultant polymerized films suggest that unlike 4 beta-MTAPc one or two amino groups might have not involved in electropolymerization in the case of 4 alpha-MTAPc. Further, the influence of surface coverage on the electrocatalytic properties of the polymerized films was studied by taking p-4 beta-Co(II)TAPc and p-4 alpha-Co(II)TAPc films as examples. The electrocatalytic oxygen reduction current was almost same at both the electrodes suggesting that only the surface species were involved in the electrocatalytic reduction of oxygen. (C) 2008 Elsevier Ltd. All rights reserved.
• FUDZIKI, MITIYA;TABEHI, XISAO;IMAMURA, SABURO;KURIXARA, TAKASI
  作者：FUDZIKI, MITIYA、TABEHI, XISAO、IMAMURA, SABURO、KURIXARA, TAKASI

  DOI：——

  日期：——