nickel(II) 1,8,15,22-tetrachlorophthalocyanine | 870685-73-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: nickel(II) 1,8,15,22-tetrachlorophthalocyanine
• CAS: 870685-73-7
• 化学式: C₃₂H₁₂Cl₄N₈Ni
• 分子量: 709.003
• InChiKey: DAHYYZDWPGSIGU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,8,15,22-tetraaminonickel phthalocyanine 在 盐酸 、 sodium nitrite 、 copper(l) chloride 作用下， 生成 nickel(II) 1,8,15,22-tetrachlorophthalocyanine
  参考文献：
  名称：

  Synthesis, spectral and magnetic susceptibility studies on tetrachloro metal(II)phthalocyanines

  摘要：

  The present paper describes a simple method for the synthesis of symmetrically substituted 1,8,15,22-tetrachloro phthalocyanines of copper, cobalt, nickel and zinc. The title complexes are synthesized from the corresponding tetraamino metal phthalocyanines by modified Sandmeyers method and in turn the tetraamino metal phthalocyanines are prepared from 3-nitrophthalic acid. The bluish-green coloured tetrachloro metal phthalocyanine complexes are characterized by elemental, electronic, IR, magnetic susceptibility and X-ray powder diffraction studies to check the purity and the structural integrity. The magnetic susceptibility studies revealed that, the experimental values are higher than that of the spin only value magnetic moment, and the presence of intermolecular co-operative effects. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2005.05.012