catena-poly[(diaqua(2-furancarboxylato-O,O')lanthanum(III))-μ-(2-furancarboxylato-O,O':O')] | 101190-28-7

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: catena-poly[(diaqua(2-furancarboxylato-O,O')lanthanum(III))-μ-(2-furancarboxylato-O,O':O')]
• 英文别名: catena-diaquatris(α-furancarboxylato)lanthanum(III)
• CAS: 101190-28-7
• 化学式: C₁₅H₁₃LaO₁₁
• 分子量: 508.167
• InChiKey: HLQXEQAKHUJAMN-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  糠酸（呋喃甲酸） 、 lanthanum(III) nitrate hexahydrate 在 NaOH 作用下， 以 乙醇 为溶剂， 生成 catena-poly[(diaqua(2-furancarboxylato-O,O')lanthanum(III))-μ-(2-furancarboxylato-O,O':O')]
  参考文献：
  名称：

  catena-Diaquatris(α-furancarboxylato)lanthanum(III)

  摘要：

  Each La3+ ion in catena-poly[[diaqua(2-furancarboxylato-O,O')lanthanum(III)]-mu-(2-furancarboxylato-O,O':O')], [La(C5H3O3)(3)(H2O)(2)](n), is coordinated to seven O atoms from furancarboxylato groups and to two O atoms of water molecules in a distorted monocapped square-antiprism configuration. The rare earth metal ions are bridged by the carboxylate groups to form an infinite two-dimensional polymeric network.

  DOI：

  10.1107/s0108270197004022