| 142541-37-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 乙烯基酸
• CAS: 142541-37-5
• 化学式: C₄O₄*Cl₂H₁₂N₄Pt
• 分子量: 446.15
• InChiKey: ZLPQVTIVDUVORE-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tetrammineplatinum(II) chloride 、 方酸 以 水 为溶剂， 生成 、
  参考文献：
  名称：

  Interactions of squaric and croconic acids with [PtL4]2+ complexes (L = NH3, L2 = ethylenediamine): oxidative properties of oxocarbon acids and crystal structure determinations

  摘要：

  Squaric (H2Sq) and croconic (H2Croc) acid (H2A) react with [PtL4]2+ (L = ammonia or L2 = ethylenediamine) to yield complexes formulating as [PtL4](HA)2. The crystal structure of the complexes [Pt(en)2](HSq)2 and [Pt(en)2](HCroc)2 have been determined using X-ray diffraction techniques. Oxidation of platinum occurred in the course of the same reaction and complexes of [PtL4Cl2]A were obtained. The X-ray determination of the structure of [Pt(NH3)4Cl2]Sq is reported. Electrochemical measurements have been performed in the solid state to support the results obtained during the oxidation process.

  DOI：

  10.1016/s0277-5387(00)83339-2