| 152778-95-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• CAS: 152778-95-5
• 化学式: C₁₄H₂₂MoN₂O₅S₄
• 分子量: 522.543
• InChiKey: WEGJTHWJXORCME-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  0.32
• 重原子数：
  26.0
• 可旋转键数：
  8.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  121.39
• 氢给体数：
  2.0
• 氢受体数：
  9.0

反应信息

• 作为产物：
  描述：

  sodium molybdate dihydrate 、 在 盐酸 作用下， 以 乙醚 、 水 为溶剂， 以15-20的产率得到
  参考文献：
  名称：

  Complexes of molybdenum(V) and molybdenum(IV) with dithiocarbamates derived from α-amino acids. Reaction kinetics in organic solvents

  摘要：

  The reaction between dithiocarbamate derivatives of alpha-amino acids (glycine. alanine. Alpha-amino-butyric acid, norvaline, valine, norleucine, leucine and isoleucine) and sodium molybdate in acid medium leads to the formation of molybdenum(V) complexes with the general formula [Mo2O3(dtc a.a.)4] . 2H2O (a.a. = amino acid). The complexes were characterized by elemental analysis, FT-IR and uv-vis spectroscopies and XPS. They are binuclear complexes with a linear oxygen bridge, the dithiocarbamate moiety acting as a bidentate ligand and thus yielding a distorted octahedral coordination for the metal cation. In organic solvents, these compounds undergo a chemical transformation, yielding complexes with the general formula [MoO(dtc a.a.)2]. whose synthesis is also described. These complexes were characterized using the same experimental techniques as above. The kinetics of transformation in organic media were studied, proposing a multi-step reaction mechanism, and the rate constants have also been determined.

  DOI：

  10.1016/s0277-5387(00)80061-3