(S)-3-[(R)-12-(5-Hexadecyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,8-dihydroxy-dodecyl]-5-methyl-5H-furan-2-one | 216580-30-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (S)-3-[(R)-12-(5-Hexadecyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,8-dihydroxy-dodecyl]-5-methyl-5H-furan-2-one
• CAS: 216580-30-2
• 化学式: C₃₈H₇₀O₆
• 分子量: 622.97
• InChiKey: XCRFEBJNOORHPP-LLSHAPRYSA-N

反应信息

• 作为反应物：
  描述：

  甲氧基-三氟甲基苯 、 (S)-3-[(R)-12-(5-Hexadecyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,8-dihydroxy-dodecyl]-5-methyl-5H-furan-2-one 在 4-二甲氨基吡啶 、 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 反应 6.0h， 生成 (R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (R)-11-(5-hexadecyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-((S)-5-methyl-2-oxo-2,5-dihydro-furan-3-ylmethyl)-7-((R)-3,3,3-trifluoro-2-methoxy-2-phenyl-propionyloxy)-undecyl ester
  参考文献：
  名称：

  Linear acetogenins from Goniothalamus donnaiensis

  摘要：

  Four linear acetogenins, donhepocin (1), 34-epi-donhepocin (1'), donhexocin and donbutocin, have been isolated from the roots of Goniothalamus donnaiensis. 1 and 1', isolated as an epimeric pair, contain a rare gamma-hydroxymethyl-gamma-lactone. Their structures have been established on the basis of spectral and chemical evidence.

  DOI：

  10.1016/s0031-9422(97)00949-7
• 作为产物：
  描述：

  2,2-二甲氧基丙烷 、 在 对甲苯磺酸 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 生成 (S)-3-[(R)-12-(5-Hexadecyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,8-dihydroxy-dodecyl]-5-methyl-5H-furan-2-one
  参考文献：
  名称：

  Linear acetogenins from Goniothalamus donnaiensis

  摘要：

  Four linear acetogenins, donhepocin (1), 34-epi-donhepocin (1'), donhexocin and donbutocin, have been isolated from the roots of Goniothalamus donnaiensis. 1 and 1', isolated as an epimeric pair, contain a rare gamma-hydroxymethyl-gamma-lactone. Their structures have been established on the basis of spectral and chemical evidence.

  DOI：

  10.1016/s0031-9422(97)00949-7