1,2-bis(2-methyl-5-(4-(N-(pentadecan-8-yl)perylene-3,4:9,10-tetracarboxybisimid)benzyl)thiophen-3-yl)hexafluorocyclopentene | 1352824-55-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 1,2-bis(2-methyl-5-(4-(N-(pentadecan-8-yl)perylene-3,4:9,10-tetracarboxybisimid)benzyl)thiophen-3-yl)hexafluorocyclopentene
• 英文别名: 7-[[4-[4-[3,3,4,4,5,5-Hexafluoro-2-[2-methyl-5-[4-[(6,8,17,19-tetraoxo-18-pentadecan-8-yl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaen-7-yl)methyl]phenyl]thiophen-3-yl]cyclopenten-1-yl]-5-methylthiophen-2-yl]phenyl]methyl]-18-pentadecan-8-yl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone；7-[[4-[4-[3,3,4,4,5,5-hexafluoro-2-[2-methyl-5-[4-[(6,8,17,19-tetraoxo-18-pentadecan-8-yl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaen-7-yl)methyl]phenyl]thiophen-3-yl]cyclopenten-1-yl]-5-methylthiophen-2-yl]phenyl]methyl]-18-pentadecan-8-yl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone
• CAS: 1352824-55-5
• 化学式: C₁₀₇H₉₈F₆N₄O₈S₂
• 分子量: 1746.1
• InChiKey: QGGVKGORGZFJTG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  28.6
• 重原子数：
  127
• 可旋转键数：
  34
• 环数：
  19.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  206
• 氢给体数：
  0
• 氢受体数：
  16

反应信息

• 作为反应物：
  描述：

  1,2-bis(2-methyl-5-(4-(N-(pentadecan-8-yl)perylene-3,4:9,10-tetracarboxybisimid)benzyl)thiophen-3-yl)hexafluorocyclopentene 生成 7-[[4-[(1R,2R)-8,8,9,9,10,10-hexafluoro-1,2-dimethyl-14-[4-[(6,8,17,19-tetraoxo-18-pentadecan-8-yl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaen-7-yl)methyl]phenyl]-3,15-dithiatetracyclo[10.3.0.02,6.07,11]pentadeca-4,6,11,13-tetraen-4-yl]phenyl]methyl]-18-pentadecan-8-yl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone
  参考文献：
  名称：

  在环境条件下运行的有机光电晶体管

  摘要：

  它需要三个步骤：利用分子三重态的光物理特性，证明了光学晶体管的关键功能，门控和放大（见图）。三单元组的两个构件是高效荧光团，而第三个构件是光致变色分子，可以通过光在两个双稳态形式之间可逆地相互转换。

  DOI：

  10.1002/anie.201104193
• 作为产物：
  描述：

  7-[[4-[(1R,2R)-8,8,9,9,10,10-hexafluoro-1,2-dimethyl-14-[4-[(6,8,17,19-tetraoxo-18-pentadecan-8-yl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaen-7-yl)methyl]phenyl]-3,15-dithiatetracyclo[10.3.0.02,6.07,11]pentadeca-4,6,11,13-tetraen-4-yl]phenyl]methyl]-18-pentadecan-8-yl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone 生成 1,2-bis(2-methyl-5-(4-(N-(pentadecan-8-yl)perylene-3,4:9,10-tetracarboxybisimid)benzyl)thiophen-3-yl)hexafluorocyclopentene
  参考文献：
  名称：

  在环境条件下运行的有机光电晶体管

  摘要：

  它需要三个步骤：利用分子三重态的光物理特性，证明了光学晶体管的关键功能，门控和放大（见图）。三单元组的两个构件是高效荧光团，而第三个构件是光致变色分子，可以通过光在两个双稳态形式之间可逆地相互转换。

  DOI：

  10.1002/anie.201104193

文献信息

• An Organic Optical Transistor Operated under Ambient Conditions
  作者：Martti Pärs、Christiane C. Hofmann、Katja Willinger、Peter Bauer、Mukundan Thelakkat、Jürgen Köhler

  DOI：10.1002/anie.201104193

  日期：2011.11.25

  It takes three: The key functionalities of an optical transistor, gating and amplification, are demonstrated exploiting the photophysical properties of a molecular triad (see picture). Two building blocks of the triad are highly efficient fluorophores, whereas the third building block is a photochromic molecule that can be reversibly interconverted between two bistable forms by light.

  它需要三个步骤：利用分子三重态的光物理特性，证明了光学晶体管的关键功能，门控和放大（见图）。三单元组的两个构件是高效荧光团，而第三个构件是光致变色分子，可以通过光在两个双稳态形式之间可逆地相互转换。