5,11-Diethyl-4,6,10,12-tetramethyl-8-methylidene-2,2-diphenyl-1,3-diaza-2-silatricyclo[7.3.0.03,7]dodeca-4,6,9,11-tetraene | 1519018-24-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: 5,11-Diethyl-4,6,10,12-tetramethyl-8-methylidene-2,2-diphenyl-1,3-diaza-2-silatricyclo[7.3.0.03,7]dodeca-4,6,9,11-tetraene
• 英文别名: 5,11-diethyl-4,6,10,12-tetramethyl-8-methylidene-2,2-diphenyl-1,3-diaza-2-silatricyclo[7.3.0.03,7]dodeca-4,6,9,11-tetraene
• CAS: 1519018-24-6
• 化学式: C₃₀H₃₄N₂Si
• 分子量: 450.699
• InChiKey: JZACAIZDEIQLQI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.68
• 重原子数：
  33
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  9.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  2,8-diethyl-1,3,5,7,9-pentamethyldipyrrin hydrochloride 在 正丁基锂 、 三乙胺 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 10.0h， 生成 5,11-Diethyl-4,6,10,12-tetramethyl-8-methylidene-2,2-diphenyl-1,3-diaza-2-silatricyclo[7.3.0.03,7]dodeca-4,6,9,11-tetraene
  参考文献：
  名称：

  Silicon Compounds of 1,1-Bis(pyrrol-2-yl)ethenes: Molecular Structures and Chemical and Spectroscopic Properties

  摘要：

  The first examples of silicon compounds of 1,1-bis(pyrrol-2-yl)ethenes have been synthesized via salt metathesis from a 2-fold lithiated dipyrromethene and different diorganodichlorosilanes (i.e., dimethyldichlorosilane, diphenyldichlorosilane, and 1,1-dichlorosilacyclobutane). Herein we report on their molecular structures, their optical properties, and some reactivity patterns.

  DOI：

  10.1021/om400868w

文献信息

• Silicon Compounds of 1,1-Bis(pyrrol-2-yl)ethenes: Molecular Structures and Chemical and Spectroscopic Properties
  作者：Alexander Kämpfe、Edwin Kroke、Jörg Wagler

  DOI：10.1021/om400868w

  日期：2014.1.13

  The first examples of silicon compounds of 1,1-bis(pyrrol-2-yl)ethenes have been synthesized via salt metathesis from a 2-fold lithiated dipyrromethene and different diorganodichlorosilanes (i.e., dimethyldichlorosilane, diphenyldichlorosilane, and 1,1-dichlorosilacyclobutane). Herein we report on their molecular structures, their optical properties, and some reactivity patterns.