2-amino-3-phenyl-1-azaazulene | 1205539-18-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: 2-amino-3-phenyl-1-azaazulene
• 英文别名: 3-Phenylcyclohepta[b]pyrrol-2-amine；3-phenylcyclohepta[b]pyrrol-2-amine
• CAS: 1205539-18-9
• 化学式: C₁₅H₁₂N₂
• 分子量: 220.274
• InChiKey: YILVOIYXPUNTHI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38.9
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-chloro-3-phenyl-1-azaazulene 、 2-amino-3-phenyl-1-azaazulene 在 tris-(dibenzylideneacetone)dipalladium(0) 、 caesium carbonate 、 4,5-双二苯基膦-9,9-二甲基氧杂蒽 作用下， 以 1,4-二氧六环 为溶剂， 反应 24.0h， 以43%的产率得到3-phenyl-N-(3-phenylcyclohepta[b]pyrrol-2-yl)cyclohepta[b]pyrrol-2-amine
  参考文献：
  名称：

  Synthesis and Complexation of Bis(1-azaazulen-2-yl)amines and Bis(1-azaazulen-2-yl) Sulfides

  摘要：

  Complexation of bis(3-phenyl-1-azaazulen-2-yl)amine with Zn(OAc)(2) and Ni(OAc)(2) was investigated, and four-coordinate bis-chelate complexes, M(II) bis[(3-phenyl-1-azaazule-2-yl)(3-phenyl-1-azaazulen-2-ylidene)aminate] (M = Zn, Ni), were obtained. Complexation of bis(1-azaazulen-2-yl) sulfide with CoCl2 gave: 2 : 1 ligand-metal complex as major product and complexation of bis(3-iodo-1-azaazulen-2-yl) sulfide with CoCl2 gave 1: 1 ligand-metal complex.

  DOI：

  10.3987/com-12-12507

文献信息

• Synthesis and Complexation of Bis(1-azaazulen-2-yl)amines and Bis(1-azaazulen-2-yl) Sulfides
  作者：Noritaka Abe、Eiko Yoshioka、Kazuya Koizumi、Kenji Nakashima、Hiroyuki Fujii、Toshihiro Murafuji、Takahiro Gunji

  DOI：10.3987/com-12-12507

  日期：——

  Complexation of bis(3-phenyl-1-azaazulen-2-yl)amine with Zn(OAc)(2) and Ni(OAc)(2) was investigated, and four-coordinate bis-chelate complexes, M(II) bis[(3-phenyl-1-azaazule-2-yl)(3-phenyl-1-azaazulen-2-ylidene)aminate] (M = Zn, Ni), were obtained. Complexation of bis(1-azaazulen-2-yl) sulfide with CoCl2 gave: 2 : 1 ligand-metal complex as major product and complexation of bis(3-iodo-1-azaazulen-2-yl) sulfide with CoCl2 gave 1: 1 ligand-metal complex.