(2,8,11,17,20,26,29,35-octakis(dodecyloxy)-3,7,12,16,21,25,30,34-octamethoxytetraphenanthro[9,10-b:9',10'-g:9'',10''-l:9''',10'''-q]porphyrinato)zinc(II) | 1359741-23-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: (2,8,11,17,20,26,29,35-octakis(dodecyloxy)-3,7,12,16,21,25,30,34-octamethoxytetraphenanthro[9,10-b:9',10'-g:9'',10''-l:9''',10'''-q]porphyrinato)zinc(II)
• CAS: 1359741-23-3
• 化学式: C₁₇₂H₂₄₄N₄O₁₆Zn
• 分子量: 2689.24
• InChiKey: IYXGYXAAVZFHFT-IOBCKEROSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,8,11,17,20,26,29,35-octakis(dodecyloxy)-3,7,12,16,21,25,30,34-octamethoxytetraphenanthro[9,10-b:9',10'-g:9'',10''-l:9''',10'''-q]porphyrin 在 zinc acetate dehydrate 作用下， 以 甲醇 、 氯仿 为溶剂， 反应 1.0h， 以100%的产率得到(2,8,11,17,20,26,29,35-octakis(dodecyloxy)-3,7,12,16,21,25,30,34-octamethoxytetraphenanthro[9,10-b:9',10'-g:9'',10''-l:9''',10'''-q]porphyrinato)zinc(II)
  参考文献：
  名称：

  Peripherally Fused Porphyrins via the Scholl Reaction: Synthesis, Self-Assembly, and Mesomorphism

  摘要：

  Oxidative coupling of activated aryl groups attached to beta-positions of the porphyrin ring provides convenient access to derivatives containing peripherally fused phenanthrene and benzo[g]chrysene units. Tetra(benzochryseno)porphyrin, reported here for the first time, contains a nonplanar, sterically locked pi system and shows very intense electronic absorptions in the Q range of the electronic spectrum. Tetraphenanthroporphyrins show a tendency to aggregate in solution. In one case, a discrete dimer is formed, whose structure was investigated spectroscopically and theoretically. Derivatives bearing long alkyl chains are mesomorphic and exhibit columnar phases (tetraphenanthroporphyrins) and a monoclinic 3D phase (tetrabenzochrysenoporphyrin). The symmetry of column packing in the columnar phases is dependent on the number of alkyl chains per molecule. X-ray diffraction measurements show that, in spite of their nonplanarity, the aromatic cores in the mesophases are tightly stacked within the column. The corresponding stacking patterns were derived from the structure of the dimer, on the basis of geometrical analysis and molecular modeling.

  DOI：

  10.1021/ja210991f