Cu(4-piperidinemethanethioldithiocarbamate)(morpholyldithiocarbamate) | 942984-71-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 恶嗪烷类
• 英文名称: Cu(4-piperidinemethanethioldithiocarbamate)(morpholyldithiocarbamate)
• 英文别名: Cu(DTCpipSH)(DTCmor)
• CAS: 942984-71-6
• 化学式: C₁₂H₂₀CuN₂OS₅
• 分子量: 432.18
• InChiKey: JIKDQBMHWBXNTL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  1.61
• 重原子数：
  21.0
• 可旋转键数：
  1.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  15.71
• 氢给体数：
  1.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  吗啉 、 二硫化碳 、 4-piperidinemethanethiol 、 copper dichloride 在 NH₃ 作用下， 以 甲醇 为溶剂， 生成 Cu(4-piperidinemethanethioldithiocarbamate)(morpholyldithiocarbamate)
  参考文献：
  名称：

  Gold Nanoparticles Enhancing Dismutation of Superoxide Radical by Its Bis(dithiocarbamato)copper(II) Shell

  摘要：

  In the past few years three topics in nanoscience have received great attention: catalytic activity of gold nanoparticles (AuNPs), their electron transfer properties, and magnetism. Although these properties could have much in common no report on their synergism has been published. Here we present 10-nm gold nanoparticles conveniently capped with a mixed self-assembled monolayer containing bis(dithiocarbamato)copper(II) complexes, which dismutate superoxide radical with extremely high efficiency (IC50 = 0.074 mu M). This behavior is interpreted as the result of an electron transfer (ET) process between AuNP core and the analyte when associated to copper(II). The ET process involving a charged AuNP core was detected by EPR and UV-vis spectroscopy.

  DOI：

  10.1021/ic101770h